TY - JOUR
T1 - Internally 1,4-phenylene-bridged meso aryl-substituted expanded porphyrins
T2 - The decaphyrin and octaphyrin cases
AU - Anand, Venkataramanarao G.
AU - Saito, Shohei
AU - Shimizu, Soji
AU - Osuka, Atsuhiro
PY - 2005/11/11
Y1 - 2005/11/11
N2 - Current affairs: Incorporation of a 1,4-phenylene bridge into meso aryl-substituted decaphyrin and octaphyrin has a profound impact on the structural and electronic properties of the macrocycles. Bridged decaphyrin has two oxidation states, one of which shows a rather strong diatropic ring current. X-ray crystal structure analyses reveal bridged octaphyrin possesses a p-quinodimethane unit, while bridged decaphyrin has a phenylene unit (see picture). (Chemical Equation Presented).
AB - Current affairs: Incorporation of a 1,4-phenylene bridge into meso aryl-substituted decaphyrin and octaphyrin has a profound impact on the structural and electronic properties of the macrocycles. Bridged decaphyrin has two oxidation states, one of which shows a rather strong diatropic ring current. X-ray crystal structure analyses reveal bridged octaphyrin possesses a p-quinodimethane unit, while bridged decaphyrin has a phenylene unit (see picture). (Chemical Equation Presented).
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U2 - 10.1002/anie.200502769
DO - 10.1002/anie.200502769
M3 - Article
C2 - 16229041
AN - SCOPUS:27844437250
SN - 1433-7851
VL - 44
SP - 7244
EP - 7248
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 44
ER -