Abstract
The intracluster proton transfer in aniline-amine complex ions is investigated by infrared photodissociation spectroscopy and density functional theory calculations. The proton acceptors include ammonia, methylamine, dimethylamine and trimethylamine in ascending order of proton affinity. The spectra of (aniline-ammonia)+ and (aniline-methylamine)+ demonstrate the persistence of the aniline ion unit in the complexes. For (aniline-dimethylamine)+ and (aniline-trimethylamine)+, the spectra imply the transformation to the anilino radical (C6H5NH) unit, suggesting the occurrence of the proton transfer.
| Original language | English |
|---|---|
| Pages (from-to) | 283-288 |
| Number of pages | 6 |
| Journal | Chemical Physics Letters |
| Volume | 359 |
| Issue number | 3-4 |
| DOIs | |
| Publication status | Published - Jun 20 2002 |
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All Science Journal Classification (ASJC) codes
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry
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Intracluster proton transfer in aniline-amine complex ions. / Inokuchi, Yoshiya; Ohashi, Kazuhiko; Honkawa, Yoshiki; Sekiya, Hiroshi; Nishi, Nobuyuki.
In: Chemical Physics Letters, Vol. 359, No. 3-4, 20.06.2002, p. 283-288.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Intracluster proton transfer in aniline-amine complex ions
AU - Inokuchi, Yoshiya
AU - Ohashi, Kazuhiko
AU - Honkawa, Yoshiki
AU - Sekiya, Hiroshi
AU - Nishi, Nobuyuki
PY - 2002/6/20
Y1 - 2002/6/20
N2 - The intracluster proton transfer in aniline-amine complex ions is investigated by infrared photodissociation spectroscopy and density functional theory calculations. The proton acceptors include ammonia, methylamine, dimethylamine and trimethylamine in ascending order of proton affinity. The spectra of (aniline-ammonia)+ and (aniline-methylamine)+ demonstrate the persistence of the aniline ion unit in the complexes. For (aniline-dimethylamine)+ and (aniline-trimethylamine)+, the spectra imply the transformation to the anilino radical (C6H5NH) unit, suggesting the occurrence of the proton transfer.
AB - The intracluster proton transfer in aniline-amine complex ions is investigated by infrared photodissociation spectroscopy and density functional theory calculations. The proton acceptors include ammonia, methylamine, dimethylamine and trimethylamine in ascending order of proton affinity. The spectra of (aniline-ammonia)+ and (aniline-methylamine)+ demonstrate the persistence of the aniline ion unit in the complexes. For (aniline-dimethylamine)+ and (aniline-trimethylamine)+, the spectra imply the transformation to the anilino radical (C6H5NH) unit, suggesting the occurrence of the proton transfer.
UR - http://www.scopus.com/inward/record.url?scp=0037142296&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0037142296&partnerID=8YFLogxK
U2 - 10.1016/S0009-2614(02)00737-6
DO - 10.1016/S0009-2614(02)00737-6
M3 - Article
AN - SCOPUS:0037142296
VL - 359
SP - 283
EP - 288
JO - Chemical Physics Letters
JF - Chemical Physics Letters
SN - 0009-2614
IS - 3-4
ER -