Intramolecular arene hydroxylation versus intermolecular olefin epoxidation by (μ-η2:η2-peroxo)dicopper(II) complex supported by dinucleating ligand

Takahiro Matsumoto; Hideki Furutachi; Masashi Kobino; Masato Tomii; Shigenori Nagatomo; Takehiko Tosha; Takao Osako; Shuhei Fujinami; Shinobu Itoh; Teizo Kitagawa; Masatatsu Suzuki

doi:10.1021/ja058117g

Intramolecular arene hydroxylation versus intermolecular olefin epoxidation by (μ-η²:η²-peroxo)dicopper(II) complex supported by dinucleating ligand

Takahiro Matsumoto, Hideki Furutachi, Masashi Kobino, Masato Tomii, Shigenori Nagatomo, Takehiko Tosha, Takao Osako, Shuhei Fujinami, Shinobu Itoh, Teizo Kitagawa, Masatatsu Suzuki

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

A discrete (μ-η²:η²-peroxo)Cu(II)₂ complex, [Cu₂(O₂)(H-L)]²⁺, is capable of performing not only intramolecular hydroxylation of a m-xylyl linker of a dinucleating ligand but also intermolecular epoxidation of styrene via electrophilic reaction to the C=C bond and hydroxylation of THF by H-atom abstraction.

Original language	English
Pages (from-to)	3874-3875
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	128
Issue number	12
DOIs	https://doi.org/10.1021/ja058117g
Publication status	Published - Mar 29 2006
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

Access to Document

10.1021/ja058117g

Cite this

Matsumoto, T., Furutachi, H., Kobino, M., Tomii, M., Nagatomo, S., Tosha, T., Osako, T., Fujinami, S., Itoh, S., Kitagawa, T., & Suzuki, M. (2006). Intramolecular arene hydroxylation versus intermolecular olefin epoxidation by (μ-η²:η²-peroxo)dicopper(II) complex supported by dinucleating ligand. Journal of the American Chemical Society, 128(12), 3874-3875. https://doi.org/10.1021/ja058117g

Intramolecular arene hydroxylation versus intermolecular olefin epoxidation by (μ-η²:η²-peroxo)dicopper(II) complex supported by dinucleating ligand. / Matsumoto, Takahiro; Furutachi, Hideki; Kobino, Masashi et al.
In: Journal of the American Chemical Society, Vol. 128, No. 12, 29.03.2006, p. 3874-3875.

Research output: Contribution to journal › Article › peer-review

Matsumoto, T, Furutachi, H, Kobino, M, Tomii, M, Nagatomo, S, Tosha, T, Osako, T, Fujinami, S, Itoh, S, Kitagawa, T & Suzuki, M 2006, 'Intramolecular arene hydroxylation versus intermolecular olefin epoxidation by (μ-η²:η²-peroxo)dicopper(II) complex supported by dinucleating ligand', Journal of the American Chemical Society, vol. 128, no. 12, pp. 3874-3875. https://doi.org/10.1021/ja058117g

@article{d94e230aa1a74181b48e2cb499ca133f,

title = "Intramolecular arene hydroxylation versus intermolecular olefin epoxidation by (μ-η2:η2-peroxo)dicopper(II) complex supported by dinucleating ligand",

abstract = "A discrete (μ-η2:η2-peroxo)Cu(II)2 complex, [Cu2(O2)(H-L)]2+, is capable of performing not only intramolecular hydroxylation of a m-xylyl linker of a dinucleating ligand but also intermolecular epoxidation of styrene via electrophilic reaction to the C=C bond and hydroxylation of THF by H-atom abstraction.",

author = "Takahiro Matsumoto and Hideki Furutachi and Masashi Kobino and Masato Tomii and Shigenori Nagatomo and Takehiko Tosha and Takao Osako and Shuhei Fujinami and Shinobu Itoh and Teizo Kitagawa and Masatatsu Suzuki",

year = "2006",

month = mar,

day = "29",

doi = "10.1021/ja058117g",

language = "English",

volume = "128",

pages = "3874--3875",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "12",

}

TY - JOUR

T1 - Intramolecular arene hydroxylation versus intermolecular olefin epoxidation by (μ-η2:η2-peroxo)dicopper(II) complex supported by dinucleating ligand

AU - Matsumoto, Takahiro

AU - Furutachi, Hideki

AU - Kobino, Masashi

AU - Tomii, Masato

AU - Nagatomo, Shigenori

AU - Tosha, Takehiko

AU - Osako, Takao

AU - Fujinami, Shuhei

AU - Itoh, Shinobu

AU - Kitagawa, Teizo

AU - Suzuki, Masatatsu

PY - 2006/3/29

Y1 - 2006/3/29

N2 - A discrete (μ-η2:η2-peroxo)Cu(II)2 complex, [Cu2(O2)(H-L)]2+, is capable of performing not only intramolecular hydroxylation of a m-xylyl linker of a dinucleating ligand but also intermolecular epoxidation of styrene via electrophilic reaction to the C=C bond and hydroxylation of THF by H-atom abstraction.

AB - A discrete (μ-η2:η2-peroxo)Cu(II)2 complex, [Cu2(O2)(H-L)]2+, is capable of performing not only intramolecular hydroxylation of a m-xylyl linker of a dinucleating ligand but also intermolecular epoxidation of styrene via electrophilic reaction to the C=C bond and hydroxylation of THF by H-atom abstraction.

UR - http://www.scopus.com/inward/record.url?scp=33645450465&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33645450465&partnerID=8YFLogxK

U2 - 10.1021/ja058117g

DO - 10.1021/ja058117g

M3 - Article

C2 - 16551071

AN - SCOPUS:33645450465

SN - 0002-7863

VL - 128

SP - 3874

EP - 3875

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 12

ER -

Intramolecular arene hydroxylation versus intermolecular olefin epoxidation by (μ-η²:η²-peroxo)dicopper(II) complex supported by dinucleating ligand

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this