Intramolecular arene hydroxylation versus intermolecular olefin epoxidation by (μ-η22-peroxo)dicopper(II) complex supported by dinucleating ligand

Takahiro Matsumoto, Hideki Furutachi, Masashi Kobino, Masato Tomii, Shigenori Nagatomo, Takehiko Tosha, Takao Osako, Shuhei Fujinami, Shinobu Itoh, Teizo Kitagawa, Masatatsu Suzuki

Research output: Contribution to journalArticle

40 Citations (Scopus)

Abstract

A discrete (μ-η22-peroxo)Cu(II)2 complex, [Cu2(O2)(H-L)]2+, is capable of performing not only intramolecular hydroxylation of a m-xylyl linker of a dinucleating ligand but also intermolecular epoxidation of styrene via electrophilic reaction to the C=C bond and hydroxylation of THF by H-atom abstraction.

Original languageEnglish
Pages (from-to)3874-3875
Number of pages2
JournalJournal of the American Chemical Society
Volume128
Issue number12
DOIs
Publication statusPublished - Mar 29 2006
Externally publishedYes

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Hydroxylation
Epoxidation
Alkenes
Olefins
Ligands
Styrene
Atoms

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Intramolecular arene hydroxylation versus intermolecular olefin epoxidation by (μ-η22-peroxo)dicopper(II) complex supported by dinucleating ligand. / Matsumoto, Takahiro; Furutachi, Hideki; Kobino, Masashi; Tomii, Masato; Nagatomo, Shigenori; Tosha, Takehiko; Osako, Takao; Fujinami, Shuhei; Itoh, Shinobu; Kitagawa, Teizo; Suzuki, Masatatsu.

In: Journal of the American Chemical Society, Vol. 128, No. 12, 29.03.2006, p. 3874-3875.

Research output: Contribution to journalArticle

Matsumoto, T, Furutachi, H, Kobino, M, Tomii, M, Nagatomo, S, Tosha, T, Osako, T, Fujinami, S, Itoh, S, Kitagawa, T & Suzuki, M 2006, 'Intramolecular arene hydroxylation versus intermolecular olefin epoxidation by (μ-η22-peroxo)dicopper(II) complex supported by dinucleating ligand', Journal of the American Chemical Society, vol. 128, no. 12, pp. 3874-3875. https://doi.org/10.1021/ja058117g
Matsumoto, Takahiro ; Furutachi, Hideki ; Kobino, Masashi ; Tomii, Masato ; Nagatomo, Shigenori ; Tosha, Takehiko ; Osako, Takao ; Fujinami, Shuhei ; Itoh, Shinobu ; Kitagawa, Teizo ; Suzuki, Masatatsu. / Intramolecular arene hydroxylation versus intermolecular olefin epoxidation by (μ-η22-peroxo)dicopper(II) complex supported by dinucleating ligand. In: Journal of the American Chemical Society. 2006 ; Vol. 128, No. 12. pp. 3874-3875.
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AU - Kobino, Masashi

AU - Tomii, Masato

AU - Nagatomo, Shigenori

AU - Tosha, Takehiko

AU - Osako, Takao

AU - Fujinami, Shuhei

AU - Itoh, Shinobu

AU - Kitagawa, Teizo

AU - Suzuki, Masatatsu

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