Intramolecular arene hydroxylation versus intermolecular olefin epoxidation by (μ-η22-peroxo)dicopper(II) complex supported by dinucleating ligand

Takahiro Matsumoto, Hideki Furutachi, Masashi Kobino, Masato Tomii, Shigenori Nagatomo, Takehiko Tosha, Takao Osako, Shuhei Fujinami, Shinobu Itoh, Teizo Kitagawa, Masatatsu Suzuki

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41 Citations (Scopus)

Abstract

A discrete (μ-η22-peroxo)Cu(II)2 complex, [Cu2(O2)(H-L)]2+, is capable of performing not only intramolecular hydroxylation of a m-xylyl linker of a dinucleating ligand but also intermolecular epoxidation of styrene via electrophilic reaction to the C=C bond and hydroxylation of THF by H-atom abstraction.

Original languageEnglish
Pages (from-to)3874-3875
Number of pages2
JournalJournal of the American Chemical Society
Volume128
Issue number12
DOIs
Publication statusPublished - Mar 29 2006
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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