Intrinsic alterations in the hydrogen desorption of Mg 2 NiH 4 by solid dissolution of titanium

Pengfei Wei, Wen Huang, Xiaoli Ding, Yongtao Li, Zheng Liu, Tingzhi Si, Kunyan Wang, Qinsheng Wang, Haiwen Li, Qingan Zhang

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Achieving rapid hydrogen desorption at low temperatures is one of the main challenges for Mg-based alloys in hydrogen storage. Here, we report that the dehydrogenation process of Mg 2 NiH 4 can be intrinsically improved with the solid dissolution of titanium into its lattices. The hydrogen desorption is suggested to be promoted by shifting the rate-limiting step from proven nucleation and/or diffusion to two-dimensional phase boundary migration based on kinetic modeling studies, for which few additions have been obtained, probably due to the understanding being confounded by other impurity phases. This alteration intrinsically results in enhanced desorption properties of Mg 2 NiH 4 when Ti is dissolved, i.e., not only does it exhibit a decreased peak desorption temperature with a reduction in the activation energy, but it also positively changes the enthalpy value in comparison with that of the pure compound. These obtained results allow for a deep understanding of how the intrinsic desorption features are enhanced by solid dissolution, and also provide insight into improving hydrogen storage in Mg-based alloys.

Original languageEnglish
Pages (from-to)8418-8426
Number of pages9
JournalDalton Transactions
Volume47
Issue number25
DOIs
Publication statusPublished - Jan 1 2018

Fingerprint

Titanium
Hydrogen
Desorption
Dissolution
Hydrogen storage
Phase boundaries
Dehydrogenation
Enthalpy
Nucleation
Activation energy
Impurities
Temperature
Kinetics

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

Cite this

Intrinsic alterations in the hydrogen desorption of Mg 2 NiH 4 by solid dissolution of titanium . / Wei, Pengfei; Huang, Wen; Ding, Xiaoli; Li, Yongtao; Liu, Zheng; Si, Tingzhi; Wang, Kunyan; Wang, Qinsheng; Li, Haiwen; Zhang, Qingan.

In: Dalton Transactions, Vol. 47, No. 25, 01.01.2018, p. 8418-8426.

Research output: Contribution to journalArticle

Wei, P, Huang, W, Ding, X, Li, Y, Liu, Z, Si, T, Wang, K, Wang, Q, Li, H & Zhang, Q 2018, ' Intrinsic alterations in the hydrogen desorption of Mg 2 NiH 4 by solid dissolution of titanium ', Dalton Transactions, vol. 47, no. 25, pp. 8418-8426. https://doi.org/10.1039/c8dt01591k
Wei, Pengfei ; Huang, Wen ; Ding, Xiaoli ; Li, Yongtao ; Liu, Zheng ; Si, Tingzhi ; Wang, Kunyan ; Wang, Qinsheng ; Li, Haiwen ; Zhang, Qingan. / Intrinsic alterations in the hydrogen desorption of Mg 2 NiH 4 by solid dissolution of titanium In: Dalton Transactions. 2018 ; Vol. 47, No. 25. pp. 8418-8426.
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