Inverted N-confused porphyrin dimer

Tomoya Ishizuka, Atsuhiro Osuka, Hiroyuki Furuta

Research output: Contribution to journalArticle

33 Citations (Scopus)

Abstract

A covalently linked N-fused porphyrin dimer was synthesized by treatment of the monomer with Ag(OCOCF3). Subsequent reaction of this dimer with NaOMe led to a porphyrin dimer with two α,β-bound ("confused") pyrrole rings (see scheme) which adopt the inverted conformation. The dimer exhibits aromaticity in spite of its highly distorted structure.

Original languageEnglish
Pages (from-to)5077-5081
Number of pages5
JournalAngewandte Chemie - International Edition
Volume43
Issue number38
DOIs
Publication statusPublished - Sep 27 2004

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Porphyrins
Dimers
Pyrroles
Conformations
Monomers

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Inverted N-confused porphyrin dimer. / Ishizuka, Tomoya; Osuka, Atsuhiro; Furuta, Hiroyuki.

In: Angewandte Chemie - International Edition, Vol. 43, No. 38, 27.09.2004, p. 5077-5081.

Research output: Contribution to journalArticle

Ishizuka, Tomoya ; Osuka, Atsuhiro ; Furuta, Hiroyuki. / Inverted N-confused porphyrin dimer. In: Angewandte Chemie - International Edition. 2004 ; Vol. 43, No. 38. pp. 5077-5081.
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