Inverted N-confused porphyrin dimer

Tomoya Ishizuka, Atsuhiro Osuka, Hiroyuki Furuta

Research output: Contribution to journalArticle

34 Citations (Scopus)

Abstract

A covalently linked N-fused porphyrin dimer was synthesized by treatment of the monomer with Ag(OCOCF3). Subsequent reaction of this dimer with NaOMe led to a porphyrin dimer with two α,β-bound ("confused") pyrrole rings (see scheme) which adopt the inverted conformation. The dimer exhibits aromaticity in spite of its highly distorted structure.

Original languageEnglish
Pages (from-to)5077-5081
Number of pages5
JournalAngewandte Chemie - International Edition
Volume43
Issue number38
DOIs
Publication statusPublished - Sep 27 2004

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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