Inverted N-confused porphyrin dimer

Tomoya Ishizuka, Atsuhiro Osuka, Hiroyuki Furuta

    Research output: Contribution to journalArticlepeer-review

    40 Citations (Scopus)

    Abstract

    A covalently linked N-fused porphyrin dimer was synthesized by treatment of the monomer with Ag(OCOCF3). Subsequent reaction of this dimer with NaOMe led to a porphyrin dimer with two α,β-bound ("confused") pyrrole rings (see scheme) which adopt the inverted conformation. The dimer exhibits aromaticity in spite of its highly distorted structure.

    Original languageEnglish
    Pages (from-to)5077-5081
    Number of pages5
    JournalAngewandte Chemie - International Edition
    Volume43
    Issue number38
    DOIs
    Publication statusPublished - Sep 27 2004

    All Science Journal Classification (ASJC) codes

    • Catalysis
    • Chemistry(all)

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