Investigation on effect of PTFE treatment on GDL micro-structure by high-resolution X-ray CT

T. Sasabe, Gen Inoue, S. Tsushima, S. Hirai, T. Tokumasu, U. Pasaogullari

Research output: Chapter in Book/Report/Conference proceedingConference contribution

10 Citations (Scopus)

Abstract

To remove liquid water from a gas diffusion layer (GDL) effectively and minimize an increase of transport resistance, hydrophobic treatment with a polytetrafluoroethylene (PTFE) is widely used. Because the GDL micro-structure has strong impact on transport properties, detailed understanding of fiber and porous network and PTFE distribution is strongly requested. To investigate correlation between the GDL micro-structure, PTFE treatment, and transport properties, micro-structure of the GDL was visualized by high-resolution X-ray computed tomography (X-ray CT). Newly designed sample holder allowed to regulate compression pressure. Visualization results with spatial resolution of 1.0 μm made it possible to distinguish carbon fibers, binder material, PTFE, and voids (air), and non-uniform distribution of PTFE was observed. Because non-uniform porosity and contact angle distribution in the direction of thickness change the liquid water morphology within the GDL, understanding and controlling the GDL micro-structure is important and manufacturing process of GDL should be scientifically developed.

Original languageEnglish
Title of host publicationPolymer Electrolyte Fuel Cells 12, PEFC 2012
Pages735-744
Number of pages10
Edition2
DOIs
Publication statusPublished - Dec 1 2012
Event12th Polymer Electrolyte Fuel Cell Symposium, PEFC 2012 - 222nd ECS Meeting - Honolulu, HI, United States
Duration: Oct 7 2012Oct 12 2012

Publication series

NameECS Transactions
Number2
Volume50
ISSN (Print)1938-5862
ISSN (Electronic)1938-6737

Other

Other12th Polymer Electrolyte Fuel Cell Symposium, PEFC 2012 - 222nd ECS Meeting
CountryUnited States
CityHonolulu, HI
Period10/7/1210/12/12

Fingerprint

Diffusion in gases
Polytetrafluoroethylenes
Tomography
X rays
Microstructure
Transport properties
Liquids
Carbon fibers
Contact angle
Binders
Water
Visualization
Porosity
Fibers
Air

All Science Journal Classification (ASJC) codes

  • Engineering(all)

Cite this

Sasabe, T., Inoue, G., Tsushima, S., Hirai, S., Tokumasu, T., & Pasaogullari, U. (2012). Investigation on effect of PTFE treatment on GDL micro-structure by high-resolution X-ray CT. In Polymer Electrolyte Fuel Cells 12, PEFC 2012 (2 ed., pp. 735-744). (ECS Transactions; Vol. 50, No. 2). https://doi.org/10.1149/05002.0735ecst

Investigation on effect of PTFE treatment on GDL micro-structure by high-resolution X-ray CT. / Sasabe, T.; Inoue, Gen; Tsushima, S.; Hirai, S.; Tokumasu, T.; Pasaogullari, U.

Polymer Electrolyte Fuel Cells 12, PEFC 2012. 2. ed. 2012. p. 735-744 (ECS Transactions; Vol. 50, No. 2).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Sasabe, T, Inoue, G, Tsushima, S, Hirai, S, Tokumasu, T & Pasaogullari, U 2012, Investigation on effect of PTFE treatment on GDL micro-structure by high-resolution X-ray CT. in Polymer Electrolyte Fuel Cells 12, PEFC 2012. 2 edn, ECS Transactions, no. 2, vol. 50, pp. 735-744, 12th Polymer Electrolyte Fuel Cell Symposium, PEFC 2012 - 222nd ECS Meeting, Honolulu, HI, United States, 10/7/12. https://doi.org/10.1149/05002.0735ecst
Sasabe T, Inoue G, Tsushima S, Hirai S, Tokumasu T, Pasaogullari U. Investigation on effect of PTFE treatment on GDL micro-structure by high-resolution X-ray CT. In Polymer Electrolyte Fuel Cells 12, PEFC 2012. 2 ed. 2012. p. 735-744. (ECS Transactions; 2). https://doi.org/10.1149/05002.0735ecst
Sasabe, T. ; Inoue, Gen ; Tsushima, S. ; Hirai, S. ; Tokumasu, T. ; Pasaogullari, U. / Investigation on effect of PTFE treatment on GDL micro-structure by high-resolution X-ray CT. Polymer Electrolyte Fuel Cells 12, PEFC 2012. 2. ed. 2012. pp. 735-744 (ECS Transactions; 2).
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