Ion-selective Response of the Azacrown-terminated Self-assembled Monolayer Formed on a Gold Electrode

Kô Takehara, Fumihiko Mukae, Hiroyuki Takemura

Research output: Contribution to journalArticlepeer-review

Abstract

Thiol derivatized aza-15-crown-5-ether (15C5) was synthesized and modified on a gold electrode surface as the self-assembled monolayer. The effects of the alkali metal ions on the CV response of the Fe(CN)63- probe ion at the modified electrode were investigated with changing alkali metal ion. The CV response was decreased in the order of Rb+ ≥ K+ > Li+ ≫ Na+. The results are discussed in relation to the interaction between the crown ring and the alkali metal ions.

Original languageEnglish
Pages (from-to)232-234
Number of pages3
JournalElectrochemistry
Volume67
Issue number3
DOIs
Publication statusPublished - Mar 1999

All Science Journal Classification (ASJC) codes

  • Electrochemistry

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