Iridium-catalysed borylation of sterically hindered C(sp3)-H bonds: Remarkable rate acceleration by a catalytic amount of potassium tert-butoxide

Toshimichi Ohmura, Takeru Torigoe, Michinori Suginome

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

The C(sp3)-H bonds located on the methyl groups of an isopropyl group participate in iridium-catalysed C-H borylation with bis(pinacolato)diboron via a significant rate acceleration caused by a catalytic amount of t-BuOK.

Original languageEnglish
Pages (from-to)6333-6336
Number of pages4
JournalChemical Communications
Volume50
Issue number48
DOIs
Publication statusPublished - May 20 2014
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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