Iridium(I) and rhodium(I) cationic complexes with triphosphinocalix[6] arene ligands: Dynamic motion with size-selective molecular encapsulation

Yasushi Obora, Yun Kui Liu, Li Hong Jiang, Kazuhiro Takenaka, Makoto Tokunaga, Yasushi Tsuji

Research output: Contribution to journalArticlepeer-review

17 Citations (Scopus)

Abstract

A novel capsule-shaped Ir(I) and Rh(I) cationic complexes with a triphosphinocalix[6]arene as a ligand were synthesized. These complexes showed dynamic behavior with size-selective molecular encapsulation, which was confirmed by variable-temperature 31P{1H} NMR measurement in the presence of various molecules.

Original languageEnglish
Pages (from-to)4-6
Number of pages3
JournalOrganometallics
Volume24
Issue number1
DOIs
Publication statusPublished - Jan 3 2005
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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