Iron-Catalyzed Acyloxyalkylation of Styrenes Using Hypervalent Iodine Reagents

Zijia Wang; Motomu Kanai; Yoichiro Kuninobu

doi:10.1021/acs.orglett.7b00923

Iron-Catalyzed Acyloxyalkylation of Styrenes Using Hypervalent Iodine Reagents

Zijia Wang, Motomu Kanai, Yoichiro Kuninobu

Department of Fundamental Organic Chemistry

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

Iron-catalyzed acyloxyalkylation of styrene derivatives using hypervalent iodine reagents was achieved. The acyloxyalkylation reaction proceeded using various types of styrenes and hypervalent iodine reagents. The acyloxyalkylated products were obtained in moderate to good yields without loss of the functional groups. The reaction proceeded via the formation of radical species derived from hypervalent iodine reagents by decarboxylation.

Original language	English
Pages (from-to)	2398-2401
Number of pages	4
Journal	Organic letters
Volume	19
Issue number	9
DOIs	https://doi.org/10.1021/acs.orglett.7b00923
Publication status	Published - May 5 2017

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/acs.orglett.7b00923

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title = "Iron-Catalyzed Acyloxyalkylation of Styrenes Using Hypervalent Iodine Reagents",

abstract = "Iron-catalyzed acyloxyalkylation of styrene derivatives using hypervalent iodine reagents was achieved. The acyloxyalkylation reaction proceeded using various types of styrenes and hypervalent iodine reagents. The acyloxyalkylated products were obtained in moderate to good yields without loss of the functional groups. The reaction proceeded via the formation of radical species derived from hypervalent iodine reagents by decarboxylation.",

author = "Zijia Wang and Motomu Kanai and Yoichiro Kuninobu",

note = "Funding Information: This work was partially supported by CREST from JST and Grant-in-Aid for Scientific Research (B) from the Ministry of Education, Culture, Sports, Science, and Technology of Japan. Publisher Copyright: {\textcopyright} 2017 American Chemical Society.",

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month = may,

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doi = "10.1021/acs.orglett.7b00923",

language = "English",

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journal = "Organic Letters",

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T1 - Iron-Catalyzed Acyloxyalkylation of Styrenes Using Hypervalent Iodine Reagents

AU - Wang, Zijia

AU - Kanai, Motomu

AU - Kuninobu, Yoichiro

N1 - Funding Information: This work was partially supported by CREST from JST and Grant-in-Aid for Scientific Research (B) from the Ministry of Education, Culture, Sports, Science, and Technology of Japan. Publisher Copyright: © 2017 American Chemical Society.

PY - 2017/5/5

Y1 - 2017/5/5

N2 - Iron-catalyzed acyloxyalkylation of styrene derivatives using hypervalent iodine reagents was achieved. The acyloxyalkylation reaction proceeded using various types of styrenes and hypervalent iodine reagents. The acyloxyalkylated products were obtained in moderate to good yields without loss of the functional groups. The reaction proceeded via the formation of radical species derived from hypervalent iodine reagents by decarboxylation.

AB - Iron-catalyzed acyloxyalkylation of styrene derivatives using hypervalent iodine reagents was achieved. The acyloxyalkylation reaction proceeded using various types of styrenes and hypervalent iodine reagents. The acyloxyalkylated products were obtained in moderate to good yields without loss of the functional groups. The reaction proceeded via the formation of radical species derived from hypervalent iodine reagents by decarboxylation.

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JO - Organic Letters

JF - Organic Letters

SN - 1523-7060

IS - 9

ER -

Iron-Catalyzed Acyloxyalkylation of Styrenes Using Hypervalent Iodine Reagents

Abstract

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