Iron promoted conjugate addition: Implication of the six-centered mechanism based on the isolation of the iron-enolate intermediate

Daisuke Noda, Yusuke Sunada, Takuji Hatakeyama, Masaharu Nakamura, Hideo Nagashima

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Treatment of (η1-mesityl)2Fe(κ2-TMEDA) (1’) with an α,β-unsaturated carbonyl compound results in 1,4-addition of the mesityl group to give an iron enolate 3 quantitatively. The Z-configuration of the enolate suggested the six-centered mechanism for the conjugate addition.

Original languageEnglish
Pages (from-to)12231-12233
Number of pages3
JournalChemical Communications
Volume48
Issue number100
DOIs
Publication statusPublished - Nov 21 2012

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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