Isolating the role of charge localization in chemical expansion: (La,Sr)(Ga,Ni)O3-x case study

N. H. Perry, J. E. Thomas, D. Marrocchelli, S. R. Bishop, H. L. Tuller

    Research output: Contribution to journalArticlepeer-review

    6 Citations (Scopus)

    Abstract

    The influence of electron localization on the chemical expansion coefficient was examined experimentally, using a model electrode material, (La,Sr)(Ga,Ni)O3-δ. Varying the Ni content yielded differing degrees of electron localization with resultant chemical expansion coefficients evaluated by dilatometry and thermogravimetric analysis in N2/O 2 mixtures at 800 °C. In agreement with prior computational predictions, a decrease in chemical expansion coefficient was observed with electron delocalization.

    Original languageEnglish
    Pages (from-to)1879-1884
    Number of pages6
    JournalECS Transactions
    Volume57
    Issue number1
    DOIs
    Publication statusPublished - 2013

    All Science Journal Classification (ASJC) codes

    • Engineering(all)

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