Isolation and crystal structure of a peroxo-bridged heme-copper complex

Takefumi Chishiro, Yuichi Shimazaki, Fumito Tani, Yoshimitsu Tachi, Yoshinori Naruta, Satoru Karasawa, Shinya Hayami, Yonezo Maeda

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Abstract

A stable bridge: A peroxo-bridged Fe-O2-Cu complex (see picture) was synthesized and isolated as crystals. The X-ray structure analysis revealed that the Fe-O2-Cu moiety has a μ-η21 coordination mode; a peroxo ligand is bound to Fe in a side-on fashion with only one oxygen atom of the peroxide bound to Cu. The two metal ions (high-spin FeIII and CuII) were strongly coupled in an antiferromagnetic fashion, thus resulting in a total spin of S = 2.

Original languageEnglish
Pages (from-to)2788-2791
Number of pages4
JournalAngewandte Chemie - International Edition
Volume42
Issue number24
DOIs
Publication statusPublished - Jun 23 2003

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All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Chishiro, T., Shimazaki, Y., Tani, F., Tachi, Y., Naruta, Y., Karasawa, S., ... Maeda, Y. (2003). Isolation and crystal structure of a peroxo-bridged heme-copper complex. Angewandte Chemie - International Edition, 42(24), 2788-2791. https://doi.org/10.1002/anie.200351415