Isolation and crystal structure of the proposed low-valent active species in the H2 activation catalytic cycle

Daisuke Inoki; Takahiro Matsumoto; Hidetaka Nakai; Seiji Ogo

doi:10.1002/ejic.201300049

Isolation and crystal structure of the proposed low-valent active species in the H₂ activation catalytic cycle

Daisuke Inoki, Takahiro Matsumoto, Hidetaka Nakai, Seiji Ogo

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

We provide confirmation of our proposed design principles for a H ₂ activation catalytic cycle by constructing a new catalyst. We have been able to obtain a crystal structure to confirm our proposition that a reduced, dinuclear species stores electrons from hydrogen molecules in a metal-metal bond.

Original language	English
Pages (from-to)	3978-3986
Number of pages	9
Journal	European Journal of Inorganic Chemistry
Issue number	22-23
DOIs	https://doi.org/10.1002/ejic.201300049
Publication status	Published - 2013

All Science Journal Classification (ASJC) codes

Inorganic Chemistry

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10.1002/ejic.201300049

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title = "Isolation and crystal structure of the proposed low-valent active species in the H2 activation catalytic cycle",

abstract = "We provide confirmation of our proposed design principles for a H 2 activation catalytic cycle by constructing a new catalyst. We have been able to obtain a crystal structure to confirm our proposition that a reduced, dinuclear species stores electrons from hydrogen molecules in a metal-metal bond.",

author = "Daisuke Inoki and Takahiro Matsumoto and Hidetaka Nakai and Seiji Ogo",

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doi = "10.1002/ejic.201300049",

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T1 - Isolation and crystal structure of the proposed low-valent active species in the H2 activation catalytic cycle

AU - Inoki, Daisuke

AU - Matsumoto, Takahiro

AU - Nakai, Hidetaka

AU - Ogo, Seiji

PY - 2013

Y1 - 2013

N2 - We provide confirmation of our proposed design principles for a H 2 activation catalytic cycle by constructing a new catalyst. We have been able to obtain a crystal structure to confirm our proposition that a reduced, dinuclear species stores electrons from hydrogen molecules in a metal-metal bond.

AB - We provide confirmation of our proposed design principles for a H 2 activation catalytic cycle by constructing a new catalyst. We have been able to obtain a crystal structure to confirm our proposition that a reduced, dinuclear species stores electrons from hydrogen molecules in a metal-metal bond.

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DO - 10.1002/ejic.201300049

M3 - Article

AN - SCOPUS:84886530957

SN - 0365-9496

SP - 3978

EP - 3986

JO - Berichte der deutschen chemischen Gesellschaft

JF - Berichte der deutschen chemischen Gesellschaft

IS - 22-23

ER -

Isolation and crystal structure of the proposed low-valent active species in the H₂ activation catalytic cycle

Abstract

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