Isolation of a MnIV acylperoxo complex and its monooxidation ability

Takahiro Kikunaga, Takahiro Matsumoto, Takehiro Ohta, Hidetaka Nakai, Yoshinori Naruta, Kwang Hyun Ahn, Yoshihito Watanabe, Seiji Ogo

    Research output: Contribution to journalArticlepeer-review

    4 Citations (Scopus)

    Abstract

    The first example of monooxygenation by a high-valent MnIV complex with a peroxide is described. A key MnIV acylperoxo intermediate, which uses m-chloroperoxybenzoic acid as the oxygen donor, is directly observed by electro-spray ionization mass spectrometry and resonance Raman spectroscopy.

    Original languageEnglish
    Pages (from-to)8356-8358
    Number of pages3
    JournalChemical Communications
    Volume49
    Issue number75
    DOIs
    Publication statusPublished - Aug 22 2013

    All Science Journal Classification (ASJC) codes

    • Catalysis
    • Electronic, Optical and Magnetic Materials
    • Ceramics and Composites
    • Chemistry(all)
    • Surfaces, Coatings and Films
    • Metals and Alloys
    • Materials Chemistry

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