Isotope analysis of oxygen in minerals using Nd/YAG laser-fluorination: The use of stainless-steel wool trap as a fluorine remover

Tasuku Akagi, Ian A. Franchi, Colin T. Pillinger

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

Oxygen from a range of minerals has been liberated by fluorination under the radiation from a Nd/ YAG laser, and the isotope ratio of oxygen measured with a conventional ratio mass-spectrometer. During the fluorination, generation of fluorine gas often takes place through the dissociation of chlorine trifluoride (CIF3) and interferes with the measurement of the isotope ratio later on. Using mercury on gold to remove the F2 also led to a loss of oxygen. A simple trap made of stainless steel wool has proved to be very effective at removing of fluorine without any measurable loss of O2. The minerals analysed include quartz, feldspar, hornblende, mica, garnet, pyroxene, olivine, and spinel. The accuracy and precision of the method was evaluated. There is good agreement with data obtained by conventional fluorination for the analyses of hornblende, garnet and spinel. In the case of quartz, feldspar and pyroxene, the laser method gave isotope ratios (18O/16O) lighter than the ratios obtained by the conventional method by less than 1‰, but its application to olivine and mica gave lighter isotope ratios by as much as 1-2‰. The precision of this method is better than 0.3‰ for all the minerals investigated.

Original languageEnglish
Pages (from-to)115-122
Number of pages8
JournalGEOCHEMICAL JOURNAL
Volume29
Issue number2
DOIs
Publication statusPublished - Jan 1 1995
Externally publishedYes

Fingerprint

Oxygen Isotopes
wool
Fluorination
fluorination
Fluorine
Stainless Steel
isotope ratios
fluorine
Wool
Isotopes
Minerals
YAG lasers
stainless steels
isotopes
laser
steel
minerals
traps
isotope
oxygen

All Science Journal Classification (ASJC) codes

  • Geophysics
  • Geochemistry and Petrology

Cite this

Isotope analysis of oxygen in minerals using Nd/YAG laser-fluorination : The use of stainless-steel wool trap as a fluorine remover. / Akagi, Tasuku; Franchi, Ian A.; Pillinger, Colin T.

In: GEOCHEMICAL JOURNAL, Vol. 29, No. 2, 01.01.1995, p. 115-122.

Research output: Contribution to journalArticle

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