Isotope dependence of the effective valence of protium and deuterium in the α phase of tantalum

K. Hashizume, Y. Kawabata, K. Fujii, M. Sugisaki

    Research output: Contribution to journalArticle

    4 Citations (Scopus)

    Abstract

    The effective valence Z* of protium and deuterium in the α phase of Ta has been measured by means of a stationary state electromigration experiment in the temperature region from 373 K to 523 K. A definite isotope dependence Z*(H) >Z*(D) has been found. The reversal of the isotope dependence to Z*(H) < Z*(D) in the temperature region below 350 K has been suggested from the temperature dependence of Z*. The direct valence Zd of H and D has been evaluated by relating the temperature dependence of Z* to that of electric resistivity, leading to the values 1.7 and 0.91 respectively. We also found that the contribution of the wind valence Zw is negative and depends on the isotopes.

    Original languageEnglish
    Pages (from-to)71-76
    Number of pages6
    JournalJournal of Alloys and Compounds
    Volume215
    Issue number1-2
    DOIs
    Publication statusPublished - Nov 1994

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    Tantalum
    Deuterium
    Isotopes
    Temperature
    Electromigration
    Electric conductivity
    Experiments

    All Science Journal Classification (ASJC) codes

    • Mechanics of Materials
    • Mechanical Engineering
    • Metals and Alloys
    • Materials Chemistry

    Cite this

    Isotope dependence of the effective valence of protium and deuterium in the α phase of tantalum. / Hashizume, K.; Kawabata, Y.; Fujii, K.; Sugisaki, M.

    In: Journal of Alloys and Compounds, Vol. 215, No. 1-2, 11.1994, p. 71-76.

    Research output: Contribution to journalArticle

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    abstract = "The effective valence Z* of protium and deuterium in the α phase of Ta has been measured by means of a stationary state electromigration experiment in the temperature region from 373 K to 523 K. A definite isotope dependence Z*(H) >Z*(D) has been found. The reversal of the isotope dependence to Z*(H) < Z*(D) in the temperature region below 350 K has been suggested from the temperature dependence of Z*. The direct valence Zd of H and D has been evaluated by relating the temperature dependence of Z* to that of electric resistivity, leading to the values 1.7 and 0.91 respectively. We also found that the contribution of the wind valence Zw is negative and depends on the isotopes.",
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    AU - Hashizume, K.

    AU - Kawabata, Y.

    AU - Fujii, K.

    AU - Sugisaki, M.

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    AB - The effective valence Z* of protium and deuterium in the α phase of Ta has been measured by means of a stationary state electromigration experiment in the temperature region from 373 K to 523 K. A definite isotope dependence Z*(H) >Z*(D) has been found. The reversal of the isotope dependence to Z*(H) < Z*(D) in the temperature region below 350 K has been suggested from the temperature dependence of Z*. The direct valence Zd of H and D has been evaluated by relating the temperature dependence of Z* to that of electric resistivity, leading to the values 1.7 and 0.91 respectively. We also found that the contribution of the wind valence Zw is negative and depends on the isotopes.

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