Isotope effects in rovibrational distributions of OH(A) and OD(A) produced by electron impact on H2O and D2O

Kenji Furuya, Fumihiro Koba, Teiichiro Ogawa

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Abstract

The OH(A-X) and OD(A-X) emission spectra have been measured by 17 eV electron impact on H2O and D2O in a supersonic free jet. Rotational temperature and relative vibrational population have been estimated from a computer simulation of the spectra by using two kinds of rotational temperatures. As a result, it is found that in the v′ = 0 level the rotational temperatures of OH(A) are identical with those of OD(A) within error, on the other hand, they are significantly different from each other in the v′= 1 level.

Original languageEnglish
Pages (from-to)665-669
Number of pages5
JournalSpectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
Volume53
Issue number5
DOIs
Publication statusPublished - Jan 1 1997

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All Science Journal Classification (ASJC) codes

  • Analytical Chemistry
  • Atomic and Molecular Physics, and Optics
  • Instrumentation
  • Spectroscopy

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