Kinetic resolution of P-Chirogenic compounds by palladium-catalyzed alcoholysis of vinyl ethers

Hisashi Itoh, Eiji Yamamoto, Shigeyuki Masaoka, Ken Sakai, Makoto Tokunaga

Research output: Contribution to journalArticlepeer-review

14 Citations (Scopus)

Abstract

The palladium-catalyzed asymmetric alcoholysis of vinyl ethers of P-chirogenic compounds has been achieved. The kinetic resolution of aryl tert-butyl(2-vinyloxyaryl)phosphinates was catalyzed by palladium/chiral diamine complexes with high selectivities (krel: 12-196).

Original languageEnglish
Pages (from-to)1796-1800
Number of pages5
JournalAdvanced Synthesis and Catalysis
Volume351
Issue number11-12
DOIs
Publication statusPublished - Aug 1 2009

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Organic Chemistry

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