Kinetic resolution of P-Chirogenic compounds by palladium-catalyzed alcoholysis of vinyl ethers

Hisashi Itoh; Eiji Yamamoto; Shigeyuki Masaoka; Ken Sakai; Makoto Tokunaga

doi:10.1002/adsc.200900304

Kinetic resolution of P-Chirogenic compounds by palladium-catalyzed alcoholysis of vinyl ethers

Hisashi Itoh, Eiji Yamamoto, Shigeyuki Masaoka, Ken Sakai, Makoto Tokunaga

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

The palladium-catalyzed asymmetric alcoholysis of vinyl ethers of P-chirogenic compounds has been achieved. The kinetic resolution of aryl tert-butyl(2-vinyloxyaryl)phosphinates was catalyzed by palladium/chiral diamine complexes with high selectivities (k_rel: 12-196).

Original language	English
Pages (from-to)	1796-1800
Number of pages	5
Journal	Advanced Synthesis and Catalysis
Volume	351
Issue number	11-12
DOIs	https://doi.org/10.1002/adsc.200900304
Publication status	Published - Aug 1 2009

All Science Journal Classification (ASJC) codes

Catalysis
Organic Chemistry

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10.1002/adsc.200900304

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title = "Kinetic resolution of P-Chirogenic compounds by palladium-catalyzed alcoholysis of vinyl ethers",

abstract = "The palladium-catalyzed asymmetric alcoholysis of vinyl ethers of P-chirogenic compounds has been achieved. The kinetic resolution of aryl tert-butyl(2-vinyloxyaryl)phosphinates was catalyzed by palladium/chiral diamine complexes with high selectivities (krel: 12-196).",

author = "Hisashi Itoh and Eiji Yamamoto and Shigeyuki Masaoka and Ken Sakai and Makoto Tokunaga",

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AU - Itoh, Hisashi

AU - Yamamoto, Eiji

AU - Masaoka, Shigeyuki

AU - Sakai, Ken

AU - Tokunaga, Makoto

PY - 2009/8/1

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N2 - The palladium-catalyzed asymmetric alcoholysis of vinyl ethers of P-chirogenic compounds has been achieved. The kinetic resolution of aryl tert-butyl(2-vinyloxyaryl)phosphinates was catalyzed by palladium/chiral diamine complexes with high selectivities (krel: 12-196).

AB - The palladium-catalyzed asymmetric alcoholysis of vinyl ethers of P-chirogenic compounds has been achieved. The kinetic resolution of aryl tert-butyl(2-vinyloxyaryl)phosphinates was catalyzed by palladium/chiral diamine complexes with high selectivities (krel: 12-196).

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DO - 10.1002/adsc.200900304

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JO - Advanced Synthesis and Catalysis

JF - Advanced Synthesis and Catalysis

IS - 11-12

ER -

Kinetic resolution of P-Chirogenic compounds by palladium-catalyzed alcoholysis of vinyl ethers

Abstract

All Science Journal Classification (ASJC) codes

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