TY - JOUR
T1 - Kinetic resolution of phosphoryl and sulfonyl esters of 1,1′-bi-2-naphthol via Pd-catalyzed alcoholysis of their vinyl ethers
AU - Sakuma, Takeshi
AU - Yamamoto, Eiji
AU - Aoyama, Hiroshi
AU - Obora, Yasushi
AU - Tsuji, Yasushi
AU - Tokunaga, Makoto
N1 - Funding Information:
The present work is supported by Grant-in-Aid for Global-COE program, ‘Science for Future Molecular Systems’ from the Ministry of Education, Culture, Science, Sports and Technology of Japan. We appreciate Professor Katsuki and his research group for permitting the use of NMR equipment.
PY - 2008/7/11
Y1 - 2008/7/11
N2 - Kinetic resolution of phosphoryl and sulfonyl esters of 1,1′-bi-2-naphthol has been achieved via the Pd-catalyzed alcoholysis of their vinyl ethers. The highest krel value reached 36.8 with substrate 3c, and (R)-3c 99.0% ee was obtained in 43% isolated yield.
AB - Kinetic resolution of phosphoryl and sulfonyl esters of 1,1′-bi-2-naphthol has been achieved via the Pd-catalyzed alcoholysis of their vinyl ethers. The highest krel value reached 36.8 with substrate 3c, and (R)-3c 99.0% ee was obtained in 43% isolated yield.
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U2 - 10.1016/j.tetasy.2008.06.034
DO - 10.1016/j.tetasy.2008.06.034
M3 - Article
AN - SCOPUS:48949114897
VL - 19
SP - 1593
EP - 1599
JO - Tetrahedron Asymmetry
JF - Tetrahedron Asymmetry
SN - 0957-4166
IS - 13
ER -