Kinetic studies of calixarene-based cyclic and non-cyclic 'super-uranophiles'

Takeshi Nagasaki, Kazuhiko Kawano, Koji Araki, Seiji Shinkai

Research output: Contribution to journalArticle

28 Citations (Scopus)

Abstract

The kinetic parameters for the binding of UO22+ to calixarene-based 'super-uranophiles', parasulphonatocalix[n]arenes (n = 5, 6 and 8:1n) and their non-cyclic analogue, 3,5-bis{[2-hydroxy-3-(2-hydroxy-3-methyl-5-sulphonatophenyl)methyl-5- sulphonatophenyl]methyl}-4-hydroxybenzenesulphonate (2) have been evaluated at 25°C and pH 10.40. The reaction of UO22+ and 2 is speeded up by a factor of 85 compared to that of UO22+ and 16.

Original languageEnglish
Pages (from-to)1325-1327
Number of pages3
JournalJournal of the Chemical Society, Perkin Transactions 2
Issue number9
Publication statusPublished - 1991

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Calixarenes
Kinetic parameters
Kinetics

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Kinetic studies of calixarene-based cyclic and non-cyclic 'super-uranophiles'. / Nagasaki, Takeshi; Kawano, Kazuhiko; Araki, Koji; Shinkai, Seiji.

In: Journal of the Chemical Society, Perkin Transactions 2, No. 9, 1991, p. 1325-1327.

Research output: Contribution to journalArticle

Nagasaki, Takeshi ; Kawano, Kazuhiko ; Araki, Koji ; Shinkai, Seiji. / Kinetic studies of calixarene-based cyclic and non-cyclic 'super-uranophiles'. In: Journal of the Chemical Society, Perkin Transactions 2. 1991 ; No. 9. pp. 1325-1327.
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