Kinetic studies of calixarene-based cyclic and non-cyclic 'super-uranophiles'

Takeshi Nagasaki, Kazuhiko Kawano, Koji Araki, Seiji Shinkai

Research output: Contribution to journalArticle

28 Citations (Scopus)

Abstract

The kinetic parameters for the binding of UO22+ to calixarene-based 'super-uranophiles', parasulphonatocalix[n]arenes (n = 5, 6 and 8:1n) and their non-cyclic analogue, 3,5-bis{[2-hydroxy-3-(2-hydroxy-3-methyl-5-sulphonatophenyl)methyl-5- sulphonatophenyl]methyl}-4-hydroxybenzenesulphonate (2) have been evaluated at 25°C and pH 10.40. The reaction of UO22+ and 2 is speeded up by a factor of 85 compared to that of UO22+ and 16.

Original languageEnglish
Pages (from-to)1325-1327
Number of pages3
JournalJournal of the Chemical Society, Perkin Transactions 2
Issue number9
DOIs
Publication statusPublished - 1991

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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