Kinetics of aqueous alteration of P0798 simulated waste glass in the presence of bentonite

K. Yamaguchi, Yaohiro Inagaki, T. Saruwatari, Kazuya Idemitsu, Tatsumi Arima, H. Yoshikawa, M. Yui

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Static aqueous alteration tests were performed with a Japanese simulated HLW glass, P0798, in the presence of bentonite in order to understand the effects of bentonite on the glass alteration kinetics and on the associated Cs release. Analogous alteration tests were performed in 0.001M NaOH solution without bentonite for comparison. The results indicated that; 1) at the initial stage of alteration up to 50 days, no remarkable difference was observed in the alteration rate between both cases "with" and "without" bentonite, 2) at the later stage beyond 50 days, however, the rate in the case "with" bentonite was larger than that in the case "without" bentonite. These results on the alteration rate were analyzed by use of a water-diffusion model. In the case "without" bentonite, a good agreement was observed between the model analysis and the experimental results at the initial stage of alteration up to 50 days, however, the model analysis deviated from the experimental results at the later stage beyond 50 days. In the case "with" bentonite, on the other hand, a good agreement was observed even at the later stage to give the value of the apparent diffusion coefficient, A of 3.5×10 -21 m 2 /s. The comparison between both cases suggests that the alteration rate is controlled by the water diffusion in both cases "with" and "without" bentonite, however, the rate is depressed in the case "without" bentonite probably by the protective effects of the alteration layer developing at the glass surface. In the case "with" bentonite, on the other hand, the alteration layer is expected to be less protective. Cesium desorption tests performed for the altered glass and bentonite indicated that most of the cesium dissolved from the glass is retained in the secondary phase of smectite developing in the precipitated layer by sorption with ion-exchange in the case "without" bentonite. In the case "with" bentonite, however, it is likely to be sorbed at bentonite surface.

Original languageEnglish
Title of host publication29th International Symposium on the Scientific Basis for Nuclear Waste Management XXIX
Pages385-392
Number of pages8
Publication statusPublished - Jul 24 2006
Event29th International Symposium on the Scientific Basis for Nuclear Waste Management XXIX - Ghent, Belgium
Duration: Sep 12 2005Sep 16 2005

Publication series

NameMaterials Research Society Symposium Proceedings
Volume932
ISSN (Print)0272-9172

Other

Other29th International Symposium on the Scientific Basis for Nuclear Waste Management XXIX
CountryBelgium
CityGhent
Period9/12/059/16/05

Fingerprint

Bentonite
bentonite
Glass
Kinetics
glass
kinetics
Cesium
cesium
Water
montmorillonite

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

Yamaguchi, K., Inagaki, Y., Saruwatari, T., Idemitsu, K., Arima, T., Yoshikawa, H., & Yui, M. (2006). Kinetics of aqueous alteration of P0798 simulated waste glass in the presence of bentonite. In 29th International Symposium on the Scientific Basis for Nuclear Waste Management XXIX (pp. 385-392). (Materials Research Society Symposium Proceedings; Vol. 932).

Kinetics of aqueous alteration of P0798 simulated waste glass in the presence of bentonite. / Yamaguchi, K.; Inagaki, Yaohiro; Saruwatari, T.; Idemitsu, Kazuya; Arima, Tatsumi; Yoshikawa, H.; Yui, M.

29th International Symposium on the Scientific Basis for Nuclear Waste Management XXIX. 2006. p. 385-392 (Materials Research Society Symposium Proceedings; Vol. 932).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Yamaguchi, K, Inagaki, Y, Saruwatari, T, Idemitsu, K, Arima, T, Yoshikawa, H & Yui, M 2006, Kinetics of aqueous alteration of P0798 simulated waste glass in the presence of bentonite. in 29th International Symposium on the Scientific Basis for Nuclear Waste Management XXIX. Materials Research Society Symposium Proceedings, vol. 932, pp. 385-392, 29th International Symposium on the Scientific Basis for Nuclear Waste Management XXIX, Ghent, Belgium, 9/12/05.
Yamaguchi K, Inagaki Y, Saruwatari T, Idemitsu K, Arima T, Yoshikawa H et al. Kinetics of aqueous alteration of P0798 simulated waste glass in the presence of bentonite. In 29th International Symposium on the Scientific Basis for Nuclear Waste Management XXIX. 2006. p. 385-392. (Materials Research Society Symposium Proceedings).
Yamaguchi, K. ; Inagaki, Yaohiro ; Saruwatari, T. ; Idemitsu, Kazuya ; Arima, Tatsumi ; Yoshikawa, H. ; Yui, M. / Kinetics of aqueous alteration of P0798 simulated waste glass in the presence of bentonite. 29th International Symposium on the Scientific Basis for Nuclear Waste Management XXIX. 2006. pp. 385-392 (Materials Research Society Symposium Proceedings).
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abstract = "Static aqueous alteration tests were performed with a Japanese simulated HLW glass, P0798, in the presence of bentonite in order to understand the effects of bentonite on the glass alteration kinetics and on the associated Cs release. Analogous alteration tests were performed in 0.001M NaOH solution without bentonite for comparison. The results indicated that; 1) at the initial stage of alteration up to 50 days, no remarkable difference was observed in the alteration rate between both cases {"}with{"} and {"}without{"} bentonite, 2) at the later stage beyond 50 days, however, the rate in the case {"}with{"} bentonite was larger than that in the case {"}without{"} bentonite. These results on the alteration rate were analyzed by use of a water-diffusion model. In the case {"}without{"} bentonite, a good agreement was observed between the model analysis and the experimental results at the initial stage of alteration up to 50 days, however, the model analysis deviated from the experimental results at the later stage beyond 50 days. In the case {"}with{"} bentonite, on the other hand, a good agreement was observed even at the later stage to give the value of the apparent diffusion coefficient, A of 3.5×10 -21 m 2 /s. The comparison between both cases suggests that the alteration rate is controlled by the water diffusion in both cases {"}with{"} and {"}without{"} bentonite, however, the rate is depressed in the case {"}without{"} bentonite probably by the protective effects of the alteration layer developing at the glass surface. In the case {"}with{"} bentonite, on the other hand, the alteration layer is expected to be less protective. Cesium desorption tests performed for the altered glass and bentonite indicated that most of the cesium dissolved from the glass is retained in the secondary phase of smectite developing in the precipitated layer by sorption with ion-exchange in the case {"}without{"} bentonite. In the case {"}with{"} bentonite, however, it is likely to be sorbed at bentonite surface.",
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AU - Inagaki, Yaohiro

AU - Saruwatari, T.

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AU - Arima, Tatsumi

AU - Yoshikawa, H.

AU - Yui, M.

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