La doped effects on structure and thermoelectric properties of Sr 2 MnMoO 6 double-perovskite oxides

Tohru Sugahara, Michitaka Ohtaki, Katsuaki Suganuma

    Research output: Contribution to journalArticle

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    Abstract

    The thermoelectric properties of the double-perovskite-type oxide Sr 2 MnMoO 6 were investigated in terms of La doping at the A-site of the oxide. The Bragg reflection of Sr 2-x La x MnMoO 6 was indexed with a monoclinic unit cell and the structure was determined in the monoclinic space group P2 1 /n, due to the good agreement between the observed and calculated patterns after Rietveld refinement. The electrical conductivity of the oxides, σ, showed a semiconductor characteristic, increasing monotonically from 0.1 to 0.5S/cm at room temperature to 5-50S/cm at 1250K. The Seebeck coefficient, S, indicated the oxides to be of n-type. The absolute values of S increased with increasing temperature. These absolute values increased at just x=0.1, and then drastically decreased with increasing x ranging from 0.3 to 1.0. The power factor of the oxides, S 2 σ, increased with increasing temperature; Sr 1.9 La 0.1 MnMoO 6 showed approximately 0.12mW/mK 2 at 1250K, which is the largest value among all the samples examined in this study. The thermal conductivities of the oxides showed a temperature independent behavior, ranging approximately 0.6-1.0W/mK, and the values were significantly low. The dimensionless figure of merit, ZT=S 2 σT/κ, increased with the increasing temperature. The highest ZT value of 0.13 was observed for Sr 1.9 La 0.1 MnMoO 6 at 1100K.

    Original languageEnglish
    Pages (from-to)282-288
    Number of pages7
    JournalJournal of Asian Ceramic Societies
    Volume1
    Issue number3
    DOIs
    Publication statusPublished - Jan 1 2013

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    Perovskite
    Oxides
    Temperature
    Rietveld refinement
    Seebeck coefficient
    perovskite
    Thermal conductivity
    Doping (additives)
    Semiconductor materials

    All Science Journal Classification (ASJC) codes

    • Ceramics and Composites

    Cite this

    La doped effects on structure and thermoelectric properties of Sr 2 MnMoO 6 double-perovskite oxides . / Sugahara, Tohru; Ohtaki, Michitaka; Suganuma, Katsuaki.

    In: Journal of Asian Ceramic Societies, Vol. 1, No. 3, 01.01.2013, p. 282-288.

    Research output: Contribution to journalArticle

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    abstract = "The thermoelectric properties of the double-perovskite-type oxide Sr 2 MnMoO 6 were investigated in terms of La doping at the A-site of the oxide. The Bragg reflection of Sr 2-x La x MnMoO 6 was indexed with a monoclinic unit cell and the structure was determined in the monoclinic space group P2 1 /n, due to the good agreement between the observed and calculated patterns after Rietveld refinement. The electrical conductivity of the oxides, σ, showed a semiconductor characteristic, increasing monotonically from 0.1 to 0.5S/cm at room temperature to 5-50S/cm at 1250K. The Seebeck coefficient, S, indicated the oxides to be of n-type. The absolute values of S increased with increasing temperature. These absolute values increased at just x=0.1, and then drastically decreased with increasing x ranging from 0.3 to 1.0. The power factor of the oxides, S 2 σ, increased with increasing temperature; Sr 1.9 La 0.1 MnMoO 6 showed approximately 0.12mW/mK 2 at 1250K, which is the largest value among all the samples examined in this study. The thermal conductivities of the oxides showed a temperature independent behavior, ranging approximately 0.6-1.0W/mK, and the values were significantly low. The dimensionless figure of merit, ZT=S 2 σT/κ, increased with the increasing temperature. The highest ZT value of 0.13 was observed for Sr 1.9 La 0.1 MnMoO 6 at 1100K.",
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    N2 - The thermoelectric properties of the double-perovskite-type oxide Sr 2 MnMoO 6 were investigated in terms of La doping at the A-site of the oxide. The Bragg reflection of Sr 2-x La x MnMoO 6 was indexed with a monoclinic unit cell and the structure was determined in the monoclinic space group P2 1 /n, due to the good agreement between the observed and calculated patterns after Rietveld refinement. The electrical conductivity of the oxides, σ, showed a semiconductor characteristic, increasing monotonically from 0.1 to 0.5S/cm at room temperature to 5-50S/cm at 1250K. The Seebeck coefficient, S, indicated the oxides to be of n-type. The absolute values of S increased with increasing temperature. These absolute values increased at just x=0.1, and then drastically decreased with increasing x ranging from 0.3 to 1.0. The power factor of the oxides, S 2 σ, increased with increasing temperature; Sr 1.9 La 0.1 MnMoO 6 showed approximately 0.12mW/mK 2 at 1250K, which is the largest value among all the samples examined in this study. The thermal conductivities of the oxides showed a temperature independent behavior, ranging approximately 0.6-1.0W/mK, and the values were significantly low. The dimensionless figure of merit, ZT=S 2 σT/κ, increased with the increasing temperature. The highest ZT value of 0.13 was observed for Sr 1.9 La 0.1 MnMoO 6 at 1100K.

    AB - The thermoelectric properties of the double-perovskite-type oxide Sr 2 MnMoO 6 were investigated in terms of La doping at the A-site of the oxide. The Bragg reflection of Sr 2-x La x MnMoO 6 was indexed with a monoclinic unit cell and the structure was determined in the monoclinic space group P2 1 /n, due to the good agreement between the observed and calculated patterns after Rietveld refinement. The electrical conductivity of the oxides, σ, showed a semiconductor characteristic, increasing monotonically from 0.1 to 0.5S/cm at room temperature to 5-50S/cm at 1250K. The Seebeck coefficient, S, indicated the oxides to be of n-type. The absolute values of S increased with increasing temperature. These absolute values increased at just x=0.1, and then drastically decreased with increasing x ranging from 0.3 to 1.0. The power factor of the oxides, S 2 σ, increased with increasing temperature; Sr 1.9 La 0.1 MnMoO 6 showed approximately 0.12mW/mK 2 at 1250K, which is the largest value among all the samples examined in this study. The thermal conductivities of the oxides showed a temperature independent behavior, ranging approximately 0.6-1.0W/mK, and the values were significantly low. The dimensionless figure of merit, ZT=S 2 σT/κ, increased with the increasing temperature. The highest ZT value of 0.13 was observed for Sr 1.9 La 0.1 MnMoO 6 at 1100K.

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