Lactols in stereoselection 1. Highly selective 1,4- and 1,5-asymmetric induction

Katsuhiko Tomooka, Tatsuyuki Okinaga, Keisuke Suzuki, Gen ichi Tsuchihashi

Research output: Contribution to journalArticle

46 Citations (Scopus)

Abstract

Nucleophilic addition to substituted γ- and δ-lactols with titanium reagents provides 1,4-syn and 1,5-syn diols in high stereoselectivity, which represents a new and simple method for the remote asymmetric induction.

Original languageEnglish
Pages (from-to)6335-6338
Number of pages4
JournalTetrahedron Letters
Volume28
Issue number50
DOIs
Publication statusPublished - 1987
Externally publishedYes

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Stereoselectivity
Titanium

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

Lactols in stereoselection 1. Highly selective 1,4- and 1,5-asymmetric induction. / Tomooka, Katsuhiko; Okinaga, Tatsuyuki; Suzuki, Keisuke; Tsuchihashi, Gen ichi.

In: Tetrahedron Letters, Vol. 28, No. 50, 1987, p. 6335-6338.

Research output: Contribution to journalArticle

Tomooka, Katsuhiko ; Okinaga, Tatsuyuki ; Suzuki, Keisuke ; Tsuchihashi, Gen ichi. / Lactols in stereoselection 1. Highly selective 1,4- and 1,5-asymmetric induction. In: Tetrahedron Letters. 1987 ; Vol. 28, No. 50. pp. 6335-6338.
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