Lactols in stereoselection 3. Highly anti-cram selective 1,2-asymmetric induction

Katsuhiko Tomooka; Tatsuyuki Okinaga; Keisuke Suzuki; Gen ichi Tsuchihashi

doi:10.1016/S0040-4039(00)99520-0

Lactols in stereoselection 3. Highly anti-cram selective 1,2-asymmetric induction

Katsuhiko Tomooka, Tatsuyuki Okinaga, Keisuke Suzuki, Gen ichi Tsuchihashi

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

Nucleophilic addition of MeTi(O-iPr)₃ to α-chiral lactols proceeds in highly diastereoselective manner. The sense of the diastereofacial selection is anti-Cram-type, which provides a new and useful method for 1,2-asymmetric induction.

Original language	English
Pages (from-to)	1563-1566
Number of pages	4
Journal	Tetrahedron Letters
Volume	30
Issue number	12
DOIs	https://doi.org/10.1016/S0040-4039(00)99520-0
Publication status	Published - 1989
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)99520-0

Cite this

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title = "Lactols in stereoselection 3. Highly anti-cram selective 1,2-asymmetric induction",

abstract = "Nucleophilic addition of MeTi(O-iPr)3 to α-chiral lactols proceeds in highly diastereoselective manner. The sense of the diastereofacial selection is anti-Cram-type, which provides a new and useful method for 1,2-asymmetric induction.",

author = "Katsuhiko Tomooka and Tatsuyuki Okinaga and Keisuke Suzuki and Tsuchihashi, {Gen ichi}",

year = "1989",

doi = "10.1016/S0040-4039(00)99520-0",

language = "English",

volume = "30",

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journal = "Tetrahedron Letters",

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number = "12",

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T1 - Lactols in stereoselection 3. Highly anti-cram selective 1,2-asymmetric induction

AU - Tomooka, Katsuhiko

AU - Okinaga, Tatsuyuki

AU - Suzuki, Keisuke

AU - Tsuchihashi, Gen ichi

PY - 1989

Y1 - 1989

N2 - Nucleophilic addition of MeTi(O-iPr)3 to α-chiral lactols proceeds in highly diastereoselective manner. The sense of the diastereofacial selection is anti-Cram-type, which provides a new and useful method for 1,2-asymmetric induction.

AB - Nucleophilic addition of MeTi(O-iPr)3 to α-chiral lactols proceeds in highly diastereoselective manner. The sense of the diastereofacial selection is anti-Cram-type, which provides a new and useful method for 1,2-asymmetric induction.

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DO - 10.1016/S0040-4039(00)99520-0

M3 - Article

AN - SCOPUS:0000210175

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 12

ER -

Lactols in stereoselection 3. Highly anti-cram selective 1,2-asymmetric induction

Abstract

All Science Journal Classification (ASJC) codes

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