Lactols in stereoselection 3. Highly anti-cram selective 1,2-asymmetric induction

Katsuhiko Tomooka, Tatsuyuki Okinaga, Keisuke Suzuki, Gen ichi Tsuchihashi

Research output: Contribution to journalArticle

24 Citations (Scopus)

Abstract

Nucleophilic addition of MeTi(O-iPr)3 to α-chiral lactols proceeds in highly diastereoselective manner. The sense of the diastereofacial selection is anti-Cram-type, which provides a new and useful method for 1,2-asymmetric induction.

Original languageEnglish
Pages (from-to)1563-1566
Number of pages4
JournalTetrahedron Letters
Volume30
Issue number12
DOIs
Publication statusPublished - Jan 1 1989
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

Lactols in stereoselection 3. Highly anti-cram selective 1,2-asymmetric induction. / Tomooka, Katsuhiko; Okinaga, Tatsuyuki; Suzuki, Keisuke; Tsuchihashi, Gen ichi.

In: Tetrahedron Letters, Vol. 30, No. 12, 01.01.1989, p. 1563-1566.

Research output: Contribution to journalArticle

Tomooka, Katsuhiko ; Okinaga, Tatsuyuki ; Suzuki, Keisuke ; Tsuchihashi, Gen ichi. / Lactols in stereoselection 3. Highly anti-cram selective 1,2-asymmetric induction. In: Tetrahedron Letters. 1989 ; Vol. 30, No. 12. pp. 1563-1566.
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