Abstract
The crystalline structures of isotactic polypropylene (iPP) thin films were investigated using grazing incident wide-angle X-ray diffraction (GIWAXD), atomic force microscopy (AFM), and transmission electron microscopy (TEM). The out-of-plane (110) reflection split with 99° inclination in the GIWAXD pattern. The film surface was covered with flat-on mother lamellae with orthogonal daughter lamellae. The cross-sectional TEM image and the fast Fourier transform-processed image showed vertically aligned daughter lamellae and cross-hatched lateral mother lamellae. Flat-on lamellae may be preferentially produced at the substrate interface, after which the mother lamellae may yield daughter lamellae from the ac plane to give vertically aligned lamellae. The daughter lamellae yield in-plane lamellae with flat-on alignment from the ac plane, resulting in the global growth of a cross-hatched lamellar structure.
Original language | English |
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Pages (from-to) | 183-188 |
Number of pages | 6 |
Journal | Polymer Journal |
Volume | 51 |
Issue number | 2 |
DOIs | |
Publication status | Published - Feb 1 2019 |
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All Science Journal Classification (ASJC) codes
- Polymers and Plastics
- Materials Chemistry
Cite this
Lamellar orientation in isotactic polypropylene thin films : a complement study via grazing incidence X-ray diffraction and surface/cross-sectional imaging. / Uchida, Kiminori; Mita, Kazuki; Higaki, Yuji; Kojio, Ken; Takahara, Atsushi.
In: Polymer Journal, Vol. 51, No. 2, 01.02.2019, p. 183-188.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Lamellar orientation in isotactic polypropylene thin films
T2 - a complement study via grazing incidence X-ray diffraction and surface/cross-sectional imaging
AU - Uchida, Kiminori
AU - Mita, Kazuki
AU - Higaki, Yuji
AU - Kojio, Ken
AU - Takahara, Atsushi
PY - 2019/2/1
Y1 - 2019/2/1
N2 - The crystalline structures of isotactic polypropylene (iPP) thin films were investigated using grazing incident wide-angle X-ray diffraction (GIWAXD), atomic force microscopy (AFM), and transmission electron microscopy (TEM). The out-of-plane (110) reflection split with 99° inclination in the GIWAXD pattern. The film surface was covered with flat-on mother lamellae with orthogonal daughter lamellae. The cross-sectional TEM image and the fast Fourier transform-processed image showed vertically aligned daughter lamellae and cross-hatched lateral mother lamellae. Flat-on lamellae may be preferentially produced at the substrate interface, after which the mother lamellae may yield daughter lamellae from the ac plane to give vertically aligned lamellae. The daughter lamellae yield in-plane lamellae with flat-on alignment from the ac plane, resulting in the global growth of a cross-hatched lamellar structure.
AB - The crystalline structures of isotactic polypropylene (iPP) thin films were investigated using grazing incident wide-angle X-ray diffraction (GIWAXD), atomic force microscopy (AFM), and transmission electron microscopy (TEM). The out-of-plane (110) reflection split with 99° inclination in the GIWAXD pattern. The film surface was covered with flat-on mother lamellae with orthogonal daughter lamellae. The cross-sectional TEM image and the fast Fourier transform-processed image showed vertically aligned daughter lamellae and cross-hatched lateral mother lamellae. Flat-on lamellae may be preferentially produced at the substrate interface, after which the mother lamellae may yield daughter lamellae from the ac plane to give vertically aligned lamellae. The daughter lamellae yield in-plane lamellae with flat-on alignment from the ac plane, resulting in the global growth of a cross-hatched lamellar structure.
UR - http://www.scopus.com/inward/record.url?scp=85055697692&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85055697692&partnerID=8YFLogxK
U2 - 10.1038/s41428-018-0138-3
DO - 10.1038/s41428-018-0138-3
M3 - Article
AN - SCOPUS:85055697692
VL - 51
SP - 183
EP - 188
JO - Polymer Journal
JF - Polymer Journal
SN - 0032-3896
IS - 2
ER -