Lanthanoid triflates catalyzed reaction of a silyl ynolate with aldimines

Mitsuru Shindo, Soichiro Oya, Yusuke Sato, Kozo Shishido

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

A silyl ynolate, prepared from α,α-dibromo ester in one-pot, reacts with N-(p-methoxyphenyl)aldimines in the presence of a catalytic amount of lanthanoid triflates to provide α,β-unsaturated amides with high E selectivity.

Original languageEnglish
Pages (from-to)545-548
Number of pages4
JournalHeterocycles
Volume52
Issue number2
DOIs
Publication statusPublished - Feb 1 2000
Externally publishedYes

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Lanthanoid Series Elements
Amides
Esters

All Science Journal Classification (ASJC) codes

  • Analytical Chemistry
  • Pharmacology
  • Organic Chemistry

Cite this

Lanthanoid triflates catalyzed reaction of a silyl ynolate with aldimines. / Shindo, Mitsuru; Oya, Soichiro; Sato, Yusuke; Shishido, Kozo.

In: Heterocycles, Vol. 52, No. 2, 01.02.2000, p. 545-548.

Research output: Contribution to journalArticle

Shindo, Mitsuru ; Oya, Soichiro ; Sato, Yusuke ; Shishido, Kozo. / Lanthanoid triflates catalyzed reaction of a silyl ynolate with aldimines. In: Heterocycles. 2000 ; Vol. 52, No. 2. pp. 545-548.
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