Large monolayer domain formed by C60-azobenzene derivative

Kei Oh-ishi; Junko Okamura; Tsutomu Ishi-i; Masahito Sano; Seiji Shinkai

doi:10.1021/la981044c

Large monolayer domain formed by C₆₀-azobenzene derivative

Kei Oh-ishi, Junko Okamura, Tsutomu Ishi-i, Masahito Sano, Seiji Shinkai

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

An experiment was conducted to synthesize a new C₆₀ amphiphile in order to obtain stable monolayers. Two factors were considered in the molecular design. First, because C₆₀ is extremely hydrophobic and easy to aggregate, a bulky and strongly hydrophilic group is desirable to anchor C₆₀ at the interface. Second, since C₆₀ has no distinct physical properties to help analyze molecular orientations, a functional group to probe aggregation sites is preferable. Based on these considerations, C₆₀ derivative was synthesized.

Original language	English
Pages (from-to)	2224-2226
Number of pages	3
Journal	Langmuir
Volume	15
Issue number	6
DOIs	https://doi.org/10.1021/la981044c
Publication status	Published - Mar 16 1999
Externally published	Yes

All Science Journal Classification (ASJC) codes

Materials Science(all)
Condensed Matter Physics
Surfaces and Interfaces
Spectroscopy
Electrochemistry

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10.1021/la981044c

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abstract = "An experiment was conducted to synthesize a new C60 amphiphile in order to obtain stable monolayers. Two factors were considered in the molecular design. First, because C60 is extremely hydrophobic and easy to aggregate, a bulky and strongly hydrophilic group is desirable to anchor C60 at the interface. Second, since C60 has no distinct physical properties to help analyze molecular orientations, a functional group to probe aggregation sites is preferable. Based on these considerations, C60 derivative was synthesized.",

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AU - Okamura, Junko

AU - Ishi-i, Tsutomu

AU - Sano, Masahito

AU - Shinkai, Seiji

PY - 1999/3/16

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