LCST and UCST behavior of poly(N-vinylacetamide-co-acrylic acid) aqueous solution

Masashi Nakashima, Yasuhisa Fukuda, Takeshi Mori, Keiji Minagawa, Masami Tanaka

Research output: Contribution to conferencePaperpeer-review

Abstract

The phase transition behavior of random copolymers of N-vinylacetamide (NVA) with Acrylic acid (AA) have been investigated. The copolymer aqueous solutions show both an upper critical solution temperature (UCST) and a lower critical solution temperature (LCST). The UCST increased and the LCST decreased with increase of salts concentration. The dual thermosensitivity was not observed at pH>3.00. This indicates that it is necessary to protonate the AA units to show the dual thermosensitivity. In short, the copolymers formed intraand inter-polymer hydrogen bondings. Intra- and inter-polymer hydrogen bondings were confirmed by FT-IR measurements.

Original languageEnglish
Number of pages1
Publication statusPublished - Dec 1 2005
Externally publishedYes
Event54th SPSJ Annual Meeting 2005 - Yokohama, Japan
Duration: May 25 2005May 27 2005

Other

Other54th SPSJ Annual Meeting 2005
Country/TerritoryJapan
CityYokohama
Period5/25/055/27/05

All Science Journal Classification (ASJC) codes

  • Engineering(all)

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