Leaching and migration of neptunium in a simulated engineered barrier system consisting of HLW glass and compacted bentonite

Yaohiro Inagaki, H. Furuya, Kazuya Idemitsu, Tatsumi Arima, H. Osako, T. Banba, T. Maeda, S. Matsumoto, I. Nomura, S. Kikkawa, M. Saito, H. Okamoto

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

In a simulated engineered barrier system consisting of a simulated HLW glass doped with 237Np, a compacted bentonite and water under reducing conditions, leaching of Np from the glass and diffusion of the leached Np through the bentonite were measured systematically. The following results were obtained: (1) The concentration of dissolved species of Np in the leachate is 10-7-10-8 M, which indicates that Np(IV) is the dominant oxidation state in the system and the concentration may be controlled by solubility of NpO2xH2O(am). (2) The presence of compacted bentonite facilitates reduction of Np(V) to Np(IV) in the system. (3) The apparent diffusion coefficient of the leached Np through the bentonite is evaluated to be lower than 1.5 × 10-13m2/s, showing that the diffusivity of Np(IV) is more than one order of magnitude lower than that of Np(V).

Original languageEnglish
Pages (from-to)168-173
Number of pages6
JournalJournal of Nuclear Materials
Volume298
Issue number1-2
DOIs
Publication statusPublished - Sep 1 2001

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Neptunium
neptunium
Bentonite
bentonite
leaching
Leaching
Glass
glass
diffusivity
solubility
diffusion coefficient
Solubility
Oxidation
oxidation
Water
water

All Science Journal Classification (ASJC) codes

  • Nuclear and High Energy Physics
  • Materials Science(all)
  • Nuclear Energy and Engineering

Cite this

Leaching and migration of neptunium in a simulated engineered barrier system consisting of HLW glass and compacted bentonite. / Inagaki, Yaohiro; Furuya, H.; Idemitsu, Kazuya; Arima, Tatsumi; Osako, H.; Banba, T.; Maeda, T.; Matsumoto, S.; Nomura, I.; Kikkawa, S.; Saito, M.; Okamoto, H.

In: Journal of Nuclear Materials, Vol. 298, No. 1-2, 01.09.2001, p. 168-173.

Research output: Contribution to journalArticle

Inagaki, Yaohiro ; Furuya, H. ; Idemitsu, Kazuya ; Arima, Tatsumi ; Osako, H. ; Banba, T. ; Maeda, T. ; Matsumoto, S. ; Nomura, I. ; Kikkawa, S. ; Saito, M. ; Okamoto, H. / Leaching and migration of neptunium in a simulated engineered barrier system consisting of HLW glass and compacted bentonite. In: Journal of Nuclear Materials. 2001 ; Vol. 298, No. 1-2. pp. 168-173.
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abstract = "In a simulated engineered barrier system consisting of a simulated HLW glass doped with 237Np, a compacted bentonite and water under reducing conditions, leaching of Np from the glass and diffusion of the leached Np through the bentonite were measured systematically. The following results were obtained: (1) The concentration of dissolved species of Np in the leachate is 10-7-10-8 M, which indicates that Np(IV) is the dominant oxidation state in the system and the concentration may be controlled by solubility of NpO2xH2O(am). (2) The presence of compacted bentonite facilitates reduction of Np(V) to Np(IV) in the system. (3) The apparent diffusion coefficient of the leached Np through the bentonite is evaluated to be lower than 1.5 × 10-13m2/s, showing that the diffusivity of Np(IV) is more than one order of magnitude lower than that of Np(V).",
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AU - Arima, Tatsumi

AU - Osako, H.

AU - Banba, T.

AU - Maeda, T.

AU - Matsumoto, S.

AU - Nomura, I.

AU - Kikkawa, S.

AU - Saito, M.

AU - Okamoto, H.

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