Lewis acid-specific polymerization behaviors in living cationic polymerization of vinyl ether with a malonate group

Yukari Oda, Tomohiro Tsujino, Shokyoku Kanaoka, Sadahito Aoshima

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

For the precision synthesis of carboxy-functional polymers, the cationic polymerization of a malonic ester-containing vinyl ether (VOEM) was examined with various Lewis acids in the presence of an added base. Living cationic polymerization was achieved using ZnCl 2, FeCl 3, and SnCl 4 in conjunction with a suitable added base, whereas TiCl 4 and Et 1.5AlCl 1.5 only led to oligomerization. Such significant differences in polymerization behavior resulted from the interactions of the diester groups with a particular Lewis acid.

Original languageEnglish
Pages (from-to)2993-2998
Number of pages6
JournalJournal of Polymer Science, Part A: Polymer Chemistry
Volume50
Issue number15
DOIs
Publication statusPublished - Aug 1 2012
Externally publishedYes

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All Science Journal Classification (ASJC) codes

  • Materials Chemistry
  • Polymers and Plastics
  • Organic Chemistry

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