Light-induced water oxidation catalyzed by an oxido-bridged triruthenium complex with a Ru-O-Ru-O-Ru motif

Yuta Tsubonouchi; Shu Lin; Alexander R. Parent; Gary W. Brudvig; Ken Sakai

doi:10.1039/c6cc02816k

Light-induced water oxidation catalyzed by an oxido-bridged triruthenium complex with a Ru-O-Ru-O-Ru motif

Yuta Tsubonouchi, Shu Lin, Alexander R. Parent, Gary W. Brudvig, Ken Sakai

Inorganic and Analytical Chemistry

Research output: Contribution to journal › Article › peer-review

33 Citations (Scopus)

Abstract

A μ-oxido-bridged triruthenium complex (RuT²⁺), formed by air-oxidation of a previously reported monoruthenium water oxidation catalyst (WOC), serves as an efficient photochemical WOC with the turnover frequency (TOF) and turnover number (TON) 0.90 s^-1 and 610, respectively. The crystal structures of RuT²⁺ and its one-electron oxidized RuT³⁺ are also reported.

Original language	English
Pages (from-to)	8018-8021
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	51
DOIs	https://doi.org/10.1039/c6cc02816k
Publication status	Published - 2016

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/c6cc02816k

Cite this

@article{34caa55ec89c444ea25157785668497b,

title = "Light-induced water oxidation catalyzed by an oxido-bridged triruthenium complex with a Ru-O-Ru-O-Ru motif",

abstract = "A μ-oxido-bridged triruthenium complex (RuT2+), formed by air-oxidation of a previously reported monoruthenium water oxidation catalyst (WOC), serves as an efficient photochemical WOC with the turnover frequency (TOF) and turnover number (TON) 0.90 s-1 and 610, respectively. The crystal structures of RuT2+ and its one-electron oxidized RuT3+ are also reported.",

author = "Yuta Tsubonouchi and Shu Lin and Parent, {Alexander R.} and Brudvig, {Gary W.} and Ken Sakai",

note = "Publisher Copyright: {\textcopyright} 2016 The Royal Society of Chemistry.",

year = "2016",

doi = "10.1039/c6cc02816k",

language = "English",

volume = "52",

pages = "8018--8021",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "51",

}

TY - JOUR

T1 - Light-induced water oxidation catalyzed by an oxido-bridged triruthenium complex with a Ru-O-Ru-O-Ru motif

AU - Tsubonouchi, Yuta

AU - Lin, Shu

AU - Parent, Alexander R.

AU - Brudvig, Gary W.

AU - Sakai, Ken

PY - 2016

Y1 - 2016

N2 - A μ-oxido-bridged triruthenium complex (RuT2+), formed by air-oxidation of a previously reported monoruthenium water oxidation catalyst (WOC), serves as an efficient photochemical WOC with the turnover frequency (TOF) and turnover number (TON) 0.90 s-1 and 610, respectively. The crystal structures of RuT2+ and its one-electron oxidized RuT3+ are also reported.

AB - A μ-oxido-bridged triruthenium complex (RuT2+), formed by air-oxidation of a previously reported monoruthenium water oxidation catalyst (WOC), serves as an efficient photochemical WOC with the turnover frequency (TOF) and turnover number (TON) 0.90 s-1 and 610, respectively. The crystal structures of RuT2+ and its one-electron oxidized RuT3+ are also reported.

UR - http://www.scopus.com/inward/record.url?scp=84975528295&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84975528295&partnerID=8YFLogxK

U2 - 10.1039/c6cc02816k

DO - 10.1039/c6cc02816k

M3 - Article

AN - SCOPUS:84975528295

SN - 1359-7345

VL - 52

SP - 8018

EP - 8021

JO - Chemical Communications

JF - Chemical Communications

IS - 51

ER -

Light-induced water oxidation catalyzed by an oxido-bridged triruthenium complex with a Ru-O-Ru-O-Ru motif

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this