Light-triggered adhesion of water-soluble polymers with a caged catechol group

Jin Nishida, Motoyasu Kobayashi, Atsushi Takahara

Research output: Contribution to journalArticlepeer-review

31 Citations (Scopus)

Abstract

An acrylamide-type copolymer containing hydroxyl, amino, and ortho-nitrobenzyl protected catechol groups was synthesized as a functional mussel adhesive protein (MAP) mimetic. The resulting copolymer was stable even in the oxidative condition. Light irradiation to aqueous solution of the copolymer induced deprotection of a caged compound to give a native catechol group and triggered an oxidative cross-linking reaction to afford the adhesive gel. Two glass plates were adhered through light-activated gelation of the polymer solution in a humid air atmosphere. A novel type of light-activated adhesive with excellent stability and light controllable activation properties was successfully fabricated by modification of the MAP mimetic copolymer.

Original languageEnglish
Pages (from-to)112-115
Number of pages4
JournalACS Macro Letters
Volume2
Issue number2
DOIs
Publication statusPublished - Feb 19 2013

All Science Journal Classification (ASJC) codes

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

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