Lithium Depletion and the Rechargeability of Li-O2 Batteries in Ether and Carbonate Electrolytes

Il Chan Jang, Shintaro Ida, Tatsumi Ishihara

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

Li metal is a highly promising candidate anode material because of its high energy density. However, Li depletion caused by the formation of a passivation layer and dendrites prevent the use of Li metal for rechargeable batteries. In this study, we investigate Li depletion in practical Li-O2 batteries by using two typical electrolytes, carbonate and ether, under high Li utilization. The ether-based solvent tetraethylene glycol dimethyl ether (TEGDME) showed greatly increased levels of Li depletion through the formation of both solid electrolyte interphase (SEI) layers and dendrites than carbonated-based solvents (ethylene carbonate/diethyl carbonate (EC/DEC)). Although TEGDME is known as a stable solvent for oxygen reduction species, it may be less appropriate as a solvent with respect to Li reactivity, which is very important for the cycle stability of Li-O2 battery systems. In contrast, although slight decomposition of EC-DEC was observed, cells constructed with EC-DEC were found to be more stable than those with TEGDME for Li-O2 batteries.

Original languageEnglish
Pages (from-to)1380-1384
Number of pages5
JournalChemElectroChem
Volume2
Issue number9
DOIs
Publication statusPublished - Sep 1 2015

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Carbonates
Lithium
Ether
Electrolytes
Ethers
Glycols
Metals
Secondary batteries
Solid electrolytes
Passivation
Dendrites (metallography)
Anodes
Oxygen
Decomposition
Ethylene
tetraglyme

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electrochemistry

Cite this

Lithium Depletion and the Rechargeability of Li-O2 Batteries in Ether and Carbonate Electrolytes. / Jang, Il Chan; Ida, Shintaro; Ishihara, Tatsumi.

In: ChemElectroChem, Vol. 2, No. 9, 01.09.2015, p. 1380-1384.

Research output: Contribution to journalArticle

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