Lithium ion conductive polymer electrolytes by side group rotation(II)

Akira Satou, Shin Nishimura, Syuuichi Urabe, Hitoshi Yamamoto, Norikazu Ueyama

Research output: Contribution to conferencePaper

Abstract

In order to improve ionic conductivity of lithium ion conductive polymer at low temperature, novel styrene derivatives (1-4) were synthesized and their ionic conductivities were measured. An ionic conductivity of polymer 1, was above 10-5 S/cm, even at -60°C. Its activation energy below 20°C exhibited 11 kJ/mol. On the other hand, that of poly(ethylene oxide) electrolyte exhibited 105 kJ/mol. The difference of the activation energy implied that lithium ion transfers in polymer electrolytes was promoted by rotation motion of the dimethoxyphenyl side group instead of segmental motion of polymer main chain.

Original languageEnglish
Number of pages1
Publication statusPublished - Dec 1 2005
Externally publishedYes
Event54th SPSJ Annual Meeting 2005 - Yokohama, Japan
Duration: May 25 2005May 27 2005

Other

Other54th SPSJ Annual Meeting 2005
CountryJapan
CityYokohama
Period5/25/055/27/05

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Lithium
Ionic conductivity
Electrolytes
Ions
Polymers
Activation energy
Polyethylene oxides
Styrene
Derivatives
Temperature

All Science Journal Classification (ASJC) codes

  • Engineering(all)

Cite this

Satou, A., Nishimura, S., Urabe, S., Yamamoto, H., & Ueyama, N. (2005). Lithium ion conductive polymer electrolytes by side group rotation(II). Paper presented at 54th SPSJ Annual Meeting 2005, Yokohama, Japan.

Lithium ion conductive polymer electrolytes by side group rotation(II). / Satou, Akira; Nishimura, Shin; Urabe, Syuuichi; Yamamoto, Hitoshi; Ueyama, Norikazu.

2005. Paper presented at 54th SPSJ Annual Meeting 2005, Yokohama, Japan.

Research output: Contribution to conferencePaper

Satou, A, Nishimura, S, Urabe, S, Yamamoto, H & Ueyama, N 2005, 'Lithium ion conductive polymer electrolytes by side group rotation(II)', Paper presented at 54th SPSJ Annual Meeting 2005, Yokohama, Japan, 5/25/05 - 5/27/05.
Satou A, Nishimura S, Urabe S, Yamamoto H, Ueyama N. Lithium ion conductive polymer electrolytes by side group rotation(II). 2005. Paper presented at 54th SPSJ Annual Meeting 2005, Yokohama, Japan.
Satou, Akira ; Nishimura, Shin ; Urabe, Syuuichi ; Yamamoto, Hitoshi ; Ueyama, Norikazu. / Lithium ion conductive polymer electrolytes by side group rotation(II). Paper presented at 54th SPSJ Annual Meeting 2005, Yokohama, Japan.1 p.
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