Lithium metal borate (LiMBO3) family of insertion materials for Li-ion batteries: a sneak peak

Prabeer Barpanda, Debasmita Dwibedi, Swatilekha Ghosh, Yongho Kee, Shigeto Okada

Research output: Contribution to journalReview article

14 Citations (Scopus)

Abstract

Rechargeable lithium-ion battery remains the leading electrochemical energy-storage device, albeit demanding steady effort of design and development of superior cathode materials. Polyanionic framework compounds are widely explored in search for such cathode contenders. Here, lithium metal borate (LiMBO3) forms a unique class of insertion materials having the lowest weight polyanion (i.e., BO3 3−), thus offering the highest possible theoretical capacity (ca. 220 mAh/g). Since the first report in 2001, LiMBO3 has rather slow progress in comparison to other polyanionic cathode systems based on PO4, SO4, and SiO4. The current review gives a sneak peak to the progress on LiMBO3 cathode systems in the last 15 years highlighting their salient features and impediments in cathode implementation. The synthesis and structural aspects of borate family are described along with the critical analysis of the electrochemical performance of borate family of insertion materials.

Original languageEnglish
Pages (from-to)1801-1812
Number of pages12
JournalIonics
Volume21
Issue number7
DOIs
Publication statusPublished - Jul 25 2015

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All Science Journal Classification (ASJC) codes

  • Chemical Engineering(all)
  • Materials Science(all)
  • Engineering(all)
  • Physics and Astronomy(all)

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