Low temperature synthesis of silicon quantum dots with plasma chemistry control in dual frequency non-thermal plasmas

Bibhuti Bhusan Sahu, Yongyi Yin, Jeon Geon Han, Masaharu Shiratani

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

The advanced materials process by non-thermal plasmas with a high plasma density allows the synthesis of small-to-big sized Si quantum dots by combining low-temperature deposition with superior crystalline quality in the background of an amorphous hydrogenated silicon nitride matrix. Here, we make quantum dot thin films in a reactive mixture of ammonia/silane/hydrogen utilizing dual-frequency capacitively coupled plasmas with high atomic hydrogen and nitrogen radical densities. Systematic data analysis using different film and plasma characterization tools reveals that the quantum dots with different sizes exhibit size dependent film properties, which are sensitively dependent on plasma characteristics. These films exhibit intense photoluminescence in the visible range with violet to orange colors and with narrow to broad widths (∼0.3-0.9 eV). The observed luminescence behavior can come from the quantum confinement effect, quasi-direct band-to-band recombination, and variation of atomic hydrogen and nitrogen radicals in the film growth network. The high luminescence yields in the visible range of the spectrum and size-tunable low-temperature synthesis with plasma and radical control make these quantum dot films good candidates for light emitting applications.

Original languageEnglish
Pages (from-to)15697-15710
Number of pages14
JournalPhysical Chemistry Chemical Physics
Volume18
Issue number23
DOIs
Publication statusPublished - Jan 1 2016

Fingerprint

plasma chemistry
Silicon
Semiconductor quantum dots
quantum dots
Plasmas
silicon
synthesis
Hydrogen
Luminescence
Nitrogen
hydrogen
Temperature
luminescence
Silanes
nitrogen
plasma control
Quantum confinement
Plasma density
Film growth
Ammonia

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Cite this

Low temperature synthesis of silicon quantum dots with plasma chemistry control in dual frequency non-thermal plasmas. / Sahu, Bibhuti Bhusan; Yin, Yongyi; Han, Jeon Geon; Shiratani, Masaharu.

In: Physical Chemistry Chemical Physics, Vol. 18, No. 23, 01.01.2016, p. 15697-15710.

Research output: Contribution to journalArticle

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