Luminescent Tb(III) and Sm(III) complexes with a 1,4,7-triazacyclononane-based tris-aryloxide ligand for high-performance oxygen sensors

Hidetaka Nakai, Masafumi Kuyama, Juncheol Seo, Takahiro Goto, Takahiro Matsumoto, Seiji Ogo

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Taking advantage of the outstanding oxygen-sensitive luminescence properties of the previously synthesised Tb(iii) complex [{(MeMeArO)3tacn}LnIII(THF)] (1Tb, Ln = Tb), herein, we have prepared an oxygen sensor based on 1Tb embedded in polystyrene film (1Tb/PS) and found that 1Tb/PS shows the highest sensitivity (I0/I100 = 14.9) and the fastest response (response/recovery time = 1.9 s/2.9 s), among the lanthanide(iii)-based oxygen sensors with f-f emission. Moreover, we have prepared the lanthanide(iii)-based colorimetric luminescent oxygen sensor (1TbSm/PS) with green-yellow-red responses, by using 1Tb and a newly synthesised oxygen-insensitive Sm(iii) complex (1Sm, Ln = Sm; Φ = 0.010 and τ = 12.2 μs).

Original languageEnglish
Pages (from-to)9126-9130
Number of pages5
JournalDalton Transactions
Volume46
Issue number28
DOIs
Publication statusPublished - 2017

Fingerprint

Oxygen sensors
Lanthanoid Series Elements
Ligands
Oxygen
Polystyrenes
Luminescence
Recovery
1,4,7-triazacyclononane

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

Cite this

Luminescent Tb(III) and Sm(III) complexes with a 1,4,7-triazacyclononane-based tris-aryloxide ligand for high-performance oxygen sensors. / Nakai, Hidetaka; Kuyama, Masafumi; Seo, Juncheol; Goto, Takahiro; Matsumoto, Takahiro; Ogo, Seiji.

In: Dalton Transactions, Vol. 46, No. 28, 2017, p. 9126-9130.

Research output: Contribution to journalArticle

@article{4625700328c4411588bdd69d08e34ae0,
title = "Luminescent Tb(III) and Sm(III) complexes with a 1,4,7-triazacyclononane-based tris-aryloxide ligand for high-performance oxygen sensors",
abstract = "Taking advantage of the outstanding oxygen-sensitive luminescence properties of the previously synthesised Tb(iii) complex [{(MeMeArO)3tacn}LnIII(THF)] (1Tb, Ln = Tb), herein, we have prepared an oxygen sensor based on 1Tb embedded in polystyrene film (1Tb/PS) and found that 1Tb/PS shows the highest sensitivity (I0/I100 = 14.9) and the fastest response (response/recovery time = 1.9 s/2.9 s), among the lanthanide(iii)-based oxygen sensors with f-f emission. Moreover, we have prepared the lanthanide(iii)-based colorimetric luminescent oxygen sensor (1TbSm/PS) with green-yellow-red responses, by using 1Tb and a newly synthesised oxygen-insensitive Sm(iii) complex (1Sm, Ln = Sm; Φ = 0.010 and τ = 12.2 μs).",
author = "Hidetaka Nakai and Masafumi Kuyama and Juncheol Seo and Takahiro Goto and Takahiro Matsumoto and Seiji Ogo",
year = "2017",
doi = "10.1039/c7dt01388d",
language = "English",
volume = "46",
pages = "9126--9130",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "28",

}

TY - JOUR

T1 - Luminescent Tb(III) and Sm(III) complexes with a 1,4,7-triazacyclononane-based tris-aryloxide ligand for high-performance oxygen sensors

AU - Nakai, Hidetaka

AU - Kuyama, Masafumi

AU - Seo, Juncheol

AU - Goto, Takahiro

AU - Matsumoto, Takahiro

AU - Ogo, Seiji

PY - 2017

Y1 - 2017

N2 - Taking advantage of the outstanding oxygen-sensitive luminescence properties of the previously synthesised Tb(iii) complex [{(MeMeArO)3tacn}LnIII(THF)] (1Tb, Ln = Tb), herein, we have prepared an oxygen sensor based on 1Tb embedded in polystyrene film (1Tb/PS) and found that 1Tb/PS shows the highest sensitivity (I0/I100 = 14.9) and the fastest response (response/recovery time = 1.9 s/2.9 s), among the lanthanide(iii)-based oxygen sensors with f-f emission. Moreover, we have prepared the lanthanide(iii)-based colorimetric luminescent oxygen sensor (1TbSm/PS) with green-yellow-red responses, by using 1Tb and a newly synthesised oxygen-insensitive Sm(iii) complex (1Sm, Ln = Sm; Φ = 0.010 and τ = 12.2 μs).

AB - Taking advantage of the outstanding oxygen-sensitive luminescence properties of the previously synthesised Tb(iii) complex [{(MeMeArO)3tacn}LnIII(THF)] (1Tb, Ln = Tb), herein, we have prepared an oxygen sensor based on 1Tb embedded in polystyrene film (1Tb/PS) and found that 1Tb/PS shows the highest sensitivity (I0/I100 = 14.9) and the fastest response (response/recovery time = 1.9 s/2.9 s), among the lanthanide(iii)-based oxygen sensors with f-f emission. Moreover, we have prepared the lanthanide(iii)-based colorimetric luminescent oxygen sensor (1TbSm/PS) with green-yellow-red responses, by using 1Tb and a newly synthesised oxygen-insensitive Sm(iii) complex (1Sm, Ln = Sm; Φ = 0.010 and τ = 12.2 μs).

UR - http://www.scopus.com/inward/record.url?scp=85024910621&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85024910621&partnerID=8YFLogxK

U2 - 10.1039/c7dt01388d

DO - 10.1039/c7dt01388d

M3 - Article

VL - 46

SP - 9126

EP - 9130

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 28

ER -