Mössbauer study of new vanadate glass with large charge-discharge capacity

Shiro Kubuki, Hitomi Masuda, Koken Matsuda, Kazuhiko Akiyama, Ayuko Kitajo, Shigeto Okada, Péter Zsabka, Zoltán Homonnay, Ernõ Kuzmann, Tetsuaki Nishida

Research output: Contribution to journalArticle

Abstract

Charge-discharge capacity and cyclicity of lithium ion battery (LIB) was evaluated in which 15Li2O·10Fe2O3·xSnO2·5P2O5·(70-x)V2O5 glass (x = 0 and 20 in mol%, abbreviated as xLFSPV) was used as a cathode. A local structure of xLFSPV glass before and after charging was investigated by 57Fe- and 119Sn-Mössbauer spectroscopies. 57Fe-Mössbauer spectrum of xLFSPV glass with 'x' of 20 was composed of a doublet with isomer shift (δ) of 0.35±0.02 mm s-1 and quadrupole splitting (Δ) of 0.88±0.03 mm s-1 due to distorted FeIIIO4 tetrahedra. 119Sn-Mössbauer spectrum of this glass consisted of a doublet with δ of 0.08±0.01 and Δ of 0.52±0.01 mms-1 due to distorted SnVIO6 octahedra. After discharging the battery from 4.5 to 1.0 V, larger δ of 0.40±0.03 mm s-1 and Δ of 0.94±0.04 mm s-1 were obtained, indicating that both iconicity of Fe-O bonds and local distortion of FeIIIO4 tetrahedra were increased. On the contrary, identical δ of 0.09±0.01 mm s-1 and Δ of 0.50±0.01 mm s-1 were observed in the 119Sn-Mössbauer spectrum of 20LFSPV glass after the discharge, indicating that chemical environment of SnIVO6 octahedra was not affected after the discharge. Charge-discharge curve of LIB containing 20LFSPV glass as a cathode active material recorded under the current density of 8.3 mA g-1 (0.011 mA cm-2) between 1.0 and 4.5 V showed a large initial charge capacity of 431.1 mAh g-1 and discharge capacity of 382.3 mAh g-1, respectively. These results indicate that 20LFSPV glass could be a new cathode active material for LIB.

Original languageEnglish
Pages (from-to)765-770
Number of pages6
JournalHyperfine Interactions
Volume226
Issue number1-3
DOIs
Publication statusPublished - Apr 2014

All Science Journal Classification (ASJC) codes

  • Atomic and Molecular Physics, and Optics
  • Nuclear and High Energy Physics
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry

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    Kubuki, S., Masuda, H., Matsuda, K., Akiyama, K., Kitajo, A., Okada, S., Zsabka, P., Homonnay, Z., Kuzmann, E., & Nishida, T. (2014). Mössbauer study of new vanadate glass with large charge-discharge capacity. Hyperfine Interactions, 226(1-3), 765-770. https://doi.org/10.1007/s10751-013-0931-5