Mössbauer study on characterization of Co[Fe(CN)5NH3] · xH2O

Y. Einaga; Z. Z. Gu; Y. Kobayashi; O. Sato; T. Iyoda; F. Ambe; K. Hashimoto; A. Fujishima

Mössbauer study on characterization of Co[Fe(CN)₅NH₃] · xH₂O

Y. Einaga, Z. Z. Gu, Y. Kobayashi, O. Sato, T. Iyoda, F. Ambe, K. Hashimoto, A. Fujishima

Research output: Contribution to journal › Article › peer-review

Abstract

The electronic states of Fe atoms in Co[Fe(CN)₅NH₃]·xH₂O were studied by means of ⁵⁷Fe Mössbauer spectroscopy. The Mössbauer spectra of Co[Fe(CN)₅NH₃]·6H₂O show the coexistence of mixed valences for the Fe atoms and a magnetic relaxation at 4 K. When water molecules were removed, electron transfer from Co to Fe occurred.

Original language	English
Pages (from-to)	159-166
Number of pages	8
Journal	Hyperfine Interactions
Volume	116
Issue number	1-4
Publication status	Published - 1998
Externally published	Yes

All Science Journal Classification (ASJC) codes

Atomic and Molecular Physics, and Optics
Nuclear and High Energy Physics
Condensed Matter Physics
Physical and Theoretical Chemistry

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title = "M{\"o}ssbauer study on characterization of Co[Fe(CN)5NH3] · xH2O",

abstract = "The electronic states of Fe atoms in Co[Fe(CN)5NH3]·xH2O were studied by means of 57Fe M{\"o}ssbauer spectroscopy. The M{\"o}ssbauer spectra of Co[Fe(CN)5NH3]·6H2O show the coexistence of mixed valences for the Fe atoms and a magnetic relaxation at 4 K. When water molecules were removed, electron transfer from Co to Fe occurred.",

author = "Y. Einaga and Gu, {Z. Z.} and Y. Kobayashi and O. Sato and T. Iyoda and F. Ambe and K. Hashimoto and A. Fujishima",

year = "1998",

language = "English",

volume = "116",

pages = "159--166",

journal = "Hyperfine Interactions",

issn = "0304-3843",

publisher = "Springer Netherlands",

number = "1-4",

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TY - JOUR

T1 - Mössbauer study on characterization of Co[Fe(CN)5NH3] · xH2O

AU - Einaga, Y.

AU - Gu, Z. Z.

AU - Kobayashi, Y.

AU - Sato, O.

AU - Iyoda, T.

AU - Ambe, F.

AU - Hashimoto, K.

AU - Fujishima, A.

PY - 1998

Y1 - 1998

N2 - The electronic states of Fe atoms in Co[Fe(CN)5NH3]·xH2O were studied by means of 57Fe Mössbauer spectroscopy. The Mössbauer spectra of Co[Fe(CN)5NH3]·6H2O show the coexistence of mixed valences for the Fe atoms and a magnetic relaxation at 4 K. When water molecules were removed, electron transfer from Co to Fe occurred.

AB - The electronic states of Fe atoms in Co[Fe(CN)5NH3]·xH2O were studied by means of 57Fe Mössbauer spectroscopy. The Mössbauer spectra of Co[Fe(CN)5NH3]·6H2O show the coexistence of mixed valences for the Fe atoms and a magnetic relaxation at 4 K. When water molecules were removed, electron transfer from Co to Fe occurred.

UR - http://www.scopus.com/inward/record.url?scp=0000352127&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0000352127&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0000352127

SN - 0304-3843

VL - 116

SP - 159

EP - 166

JO - Hyperfine Interactions

JF - Hyperfine Interactions

IS - 1-4

ER -

Mössbauer study on characterization of Co[Fe(CN)₅NH₃] · xH₂O

Abstract

All Science Journal Classification (ASJC) codes

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