Mössbauer study on characterization of Co[Fe(CN)5NH3] · xH2O

Y. Einaga, Z. Z. Gu, Y. Kobayashi, O. Sato, T. Iyoda, F. Ambe, K. Hashimoto, A. Fujishima

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Abstract

The electronic states of Fe atoms in Co[Fe(CN)5NH3]·xH2O were studied by means of 57Fe Mössbauer spectroscopy. The Mössbauer spectra of Co[Fe(CN)5NH3]·6H2O show the coexistence of mixed valences for the Fe atoms and a magnetic relaxation at 4 K. When water molecules were removed, electron transfer from Co to Fe occurred.

Original languageEnglish
Pages (from-to)159-166
Number of pages8
JournalHyperfine Interactions
Volume116
Issue number1-4
Publication statusPublished - Dec 1 1998
Externally publishedYes

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All Science Journal Classification (ASJC) codes

  • Atomic and Molecular Physics, and Optics
  • Nuclear and High Energy Physics
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry

Cite this

Einaga, Y., Gu, Z. Z., Kobayashi, Y., Sato, O., Iyoda, T., Ambe, F., ... Fujishima, A. (1998). Mössbauer study on characterization of Co[Fe(CN)5NH3] · xH2O. Hyperfine Interactions, 116(1-4), 159-166.