Magnetic heat capacity of TDAE-C60

Kazuyoshi Tanaka, Toshiaki Tanaka, Tooru Atake, Kazunari Yoshizawa, Kenji Okahara, Tohru Sato, Tokio Yamabe

Research output: Contribution to journalArticlepeer-review

13 Citations (Scopus)

Abstract

The heat capacity of TDAE-C60 (TDAE: tetrakis(dimethylamino)ethylene) was measured between 5 and 100 K using an adiabatic calorimeter. The magnetic phase transition was detected as a broad heat capacity peak at 12.5 K. The enthalpy and entropy of transition are 0.43 kJ mol and 34 J K mol, respectively. Such a large value of the entropy of transition compared with 2R1n 2 = 11.5 J K mol expected for a localized spin- 1 2 system probably reflects the multi-state ofC-60 due to dynamic Jahn-Teller distortion in the high-temperature region above Tc.

Original languageEnglish
Pages (from-to)271-275
Number of pages5
JournalChemical Physics Letters
Volume230
Issue number3
DOIs
Publication statusPublished - Nov 25 1994
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Fingerprint Dive into the research topics of 'Magnetic heat capacity of TDAE-C<sub>60</sub>'. Together they form a unique fingerprint.

Cite this