Magnetic Properties of 1,3,5-Tris[bis(p-methoxyphenyl)ainino]benzene Cation Radicals

Kazunari Yoshizawa, Masashi Hatanaka, Hiroki Ago, Kazuyoshi Tanaka, Tokio Yamabe

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

In order to pursue the possibility of charge-transfer organic ferromagnets, magnetic properties of the monocationic ClO4- and BF4-salts of a triaminobenzene derivative, 1,3,5-tris[bis(p-methoxyphenyl)amino]benzene (TBMAB), were characterized by means of ESR and a Faraday-type magnetic balance. MNDO-PM3 calculations predicted 1,3,5-tris(diphenylamino)benzene (TDAB) dication and trication to be ground-state triplet and quartet, respectively. Thus these triaminobenzenes fulfill the necessary precondition for the appearance of intermolecular ferromagnetic coupling based on so-called McConnell's second model. Negative Weiss constants (-1 to 0 K) and low spin concentrations (7-8 %) were observed for TBMAB-ClO4 and TBMAB-BF4, although, according to this rule, intermolecular ferromagnetic coupling is expected to occur for these systems.

Original languageEnglish
Pages (from-to)1417-1422
Number of pages6
JournalBulletin of the Chemical Society of Japan
Volume69
Issue number5
DOIs
Publication statusPublished - Jan 1 1996
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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