Magnetically Responsive Polymer Network Constructed by Poly(acrylic acid) and Holmium

Michinari Kohri; Kenshi Yanagimoto; Kotona Kohaku; Shohei Shiomoto; Motoyasu Kobayashi; Akira Imai; Fumiyuki Shiba; Tatsuo Taniguchi; Keiki Kishikawa

doi:10.1021/acs.macromol.8b01550

Magnetically Responsive Polymer Network Constructed by Poly(acrylic acid) and Holmium

Michinari Kohri, Kenshi Yanagimoto, Kotona Kohaku, Shohei Shiomoto, Motoyasu Kobayashi, Akira Imai, Fumiyuki Shiba, Tatsuo Taniguchi, Keiki Kishikawa

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

Holmium (Ho), one of the lanthanide elements, shows a high magnetic moment. Here we present a simple, yet highly potential approach for preparing polymer-based magnetic materials from a three-dimensional polymer network composed with poly(acrylic acid) and Ho showing trivalent nature. We have successfully prepared a magnetic polymer network that reacts directly to a magnet by three-dimensionally immobilizing Ho in the polymer matrix. The present method allowed a preparation of wide range of magnetic materials using polymeric scaffolds, e.g., polymer-grafted particles and cross-linked polymer gels. As a result of the high Ho content, these materials responded quickly to the magnet. The discovery of a method to prepare magnetic materials will provide flexibility in materials design and greatly expand the scope of application of magnetic materials.

Original language	English
Pages (from-to)	6740-6745
Number of pages	6
Journal	Macromolecules
Volume	51
Issue number	17
DOIs	https://doi.org/10.1021/acs.macromol.8b01550
Publication status	Published - Sep 11 2018
Externally published	Yes

All Science Journal Classification (ASJC) codes

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1021/acs.macromol.8b01550

Cite this

@article{c2edcdac0d0f4b1aae4ce8c772334072,

title = "Magnetically Responsive Polymer Network Constructed by Poly(acrylic acid) and Holmium",

abstract = "Holmium (Ho), one of the lanthanide elements, shows a high magnetic moment. Here we present a simple, yet highly potential approach for preparing polymer-based magnetic materials from a three-dimensional polymer network composed with poly(acrylic acid) and Ho showing trivalent nature. We have successfully prepared a magnetic polymer network that reacts directly to a magnet by three-dimensionally immobilizing Ho in the polymer matrix. The present method allowed a preparation of wide range of magnetic materials using polymeric scaffolds, e.g., polymer-grafted particles and cross-linked polymer gels. As a result of the high Ho content, these materials responded quickly to the magnet. The discovery of a method to prepare magnetic materials will provide flexibility in materials design and greatly expand the scope of application of magnetic materials.",

author = "Michinari Kohri and Kenshi Yanagimoto and Kotona Kohaku and Shohei Shiomoto and Motoyasu Kobayashi and Akira Imai and Fumiyuki Shiba and Tatsuo Taniguchi and Keiki Kishikawa",

note = "Funding Information: M.K. acknowledges the support of JSPS KAKENHI (Grant 16K14072), the Mazda Foundation, and the Mitsui Chemical Company Award in Synthetic Organic Chemistry, Japan. We thank Prof. Kyoichi Saito and Ms. Shoko Naruke of Chiba University for ICP-AES measurements. We acknowledge Nissan Chemical Industries, Ltd., and Sanyo Chemical Industries, Ltd., for providing reagents. Publisher Copyright: Copyright {\textcopyright} 2018 American Chemical Society.",

year = "2018",

month = sep,

day = "11",

doi = "10.1021/acs.macromol.8b01550",

language = "English",

volume = "51",

pages = "6740--6745",

journal = "Macromolecules",

issn = "0024-9297",

publisher = "American Chemical Society",

number = "17",

}

TY - JOUR

T1 - Magnetically Responsive Polymer Network Constructed by Poly(acrylic acid) and Holmium

AU - Kohri, Michinari

AU - Yanagimoto, Kenshi

AU - Kohaku, Kotona

AU - Shiomoto, Shohei

AU - Kobayashi, Motoyasu

AU - Imai, Akira

AU - Shiba, Fumiyuki

AU - Taniguchi, Tatsuo

AU - Kishikawa, Keiki

N1 - Funding Information: M.K. acknowledges the support of JSPS KAKENHI (Grant 16K14072), the Mazda Foundation, and the Mitsui Chemical Company Award in Synthetic Organic Chemistry, Japan. We thank Prof. Kyoichi Saito and Ms. Shoko Naruke of Chiba University for ICP-AES measurements. We acknowledge Nissan Chemical Industries, Ltd., and Sanyo Chemical Industries, Ltd., for providing reagents. Publisher Copyright: Copyright © 2018 American Chemical Society.

PY - 2018/9/11

Y1 - 2018/9/11

N2 - Holmium (Ho), one of the lanthanide elements, shows a high magnetic moment. Here we present a simple, yet highly potential approach for preparing polymer-based magnetic materials from a three-dimensional polymer network composed with poly(acrylic acid) and Ho showing trivalent nature. We have successfully prepared a magnetic polymer network that reacts directly to a magnet by three-dimensionally immobilizing Ho in the polymer matrix. The present method allowed a preparation of wide range of magnetic materials using polymeric scaffolds, e.g., polymer-grafted particles and cross-linked polymer gels. As a result of the high Ho content, these materials responded quickly to the magnet. The discovery of a method to prepare magnetic materials will provide flexibility in materials design and greatly expand the scope of application of magnetic materials.

AB - Holmium (Ho), one of the lanthanide elements, shows a high magnetic moment. Here we present a simple, yet highly potential approach for preparing polymer-based magnetic materials from a three-dimensional polymer network composed with poly(acrylic acid) and Ho showing trivalent nature. We have successfully prepared a magnetic polymer network that reacts directly to a magnet by three-dimensionally immobilizing Ho in the polymer matrix. The present method allowed a preparation of wide range of magnetic materials using polymeric scaffolds, e.g., polymer-grafted particles and cross-linked polymer gels. As a result of the high Ho content, these materials responded quickly to the magnet. The discovery of a method to prepare magnetic materials will provide flexibility in materials design and greatly expand the scope of application of magnetic materials.

UR - http://www.scopus.com/inward/record.url?scp=85052868087&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85052868087&partnerID=8YFLogxK

U2 - 10.1021/acs.macromol.8b01550

DO - 10.1021/acs.macromol.8b01550

M3 - Article

AN - SCOPUS:85052868087

VL - 51

SP - 6740

EP - 6745

JO - Macromolecules

JF - Macromolecules

SN - 0024-9297

IS - 17

ER -

Magnetically Responsive Polymer Network Constructed by Poly(acrylic acid) and Holmium

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this