TY - JOUR
T1 - Manganese-catalyzed cleavage of a carbon-carbon single bond between carbonyl carbon and α-carbon atoms of ketones
AU - Kuninobu, Yoichiro
AU - Uesugi, Tadamasa
AU - Kawata, Atsushi
AU - Takai, Kazuhiko
N1 - Copyright:
Copyright 2011 Elsevier B.V., All rights reserved.
PY - 2011/10/24
Y1 - 2011/10/24
N2 - Singled out: Treatment of ketones with carbodiimides in the presence of a catalytic amount of either [{HMn(CO)4}3] or [Mn 2(CO)10] gave amides in good to excellent yields. In this reaction, the carbon-carbon single bond of a ketone is cleaved efficiently. The reaction also proceeded by using isocyanates instead of carbodiimides.
AB - Singled out: Treatment of ketones with carbodiimides in the presence of a catalytic amount of either [{HMn(CO)4}3] or [Mn 2(CO)10] gave amides in good to excellent yields. In this reaction, the carbon-carbon single bond of a ketone is cleaved efficiently. The reaction also proceeded by using isocyanates instead of carbodiimides.
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U2 - 10.1002/anie.201104704
DO - 10.1002/anie.201104704
M3 - Article
C2 - 21910198
AN - SCOPUS:80055008394
VL - 50
SP - 10406
EP - 10408
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 44
ER -