Manganese/bipyridine-catalyzed non-directed C(sp3)–H bromination using NBS and TMSN3

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Abstract

A Mn(II)/bipyridine-catalyzed bromination reaction of unactivated aliphatic C(sp3)−H bonds has been developed using N-bromosuccinimide (NBS) as the brominating reagent. The reaction proceeded in moderate-to-good yield, even on a gram scale. The introduced bromine atom can be converted into fluorine and allyl groups.

Original languageEnglish
Pages (from-to)885-890
Number of pages6
JournalBeilstein Journal of Organic Chemistry
Volume17
DOIs
Publication statusPublished - Apr 22 2021

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

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