Manganese(III)-based oxidative free-radical reaction of α-allyl-β-keto ester with molecular oxygen

Takashi Ohshima, Mikiko Sodeoka, Masakatsu Shibasaki

Research output: Contribution to journalArticlepeer-review

25 Citations (Scopus)

Abstract

Oxidative reactions of α-allyl-β-keto esters 5 with Mn(OAc)3·2H2O give the δ-hydroxy-β-,γ-unsaturated-α-keto esters 6 in good yields. The mechanism of this reaction is discussed.

Original languageEnglish
Pages (from-to)8509-8512
Number of pages4
JournalTetrahedron Letters
Volume34
Issue number52
DOIs
Publication statusPublished - 1993
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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