Measurement and correlation of isoprene-maleic anhydride reaction rate in hexane-nitrobenzene mixture

Yusuke Inoue, Tomotaka Nishikawa, Masaki Sato, Yoshio Iwai, Yasuhiko Arai, Haruo Kato

Research output: Contribution to journalArticle

Abstract

Reaction rates for the Diels-Alder reaction of isoprene with maleic anhydride in the hexane-nitrobenzene mixed solvent were measured at 308.15 K. By using a reaction rate equation derived from the transition state theory coupled with the regular solution model, the reaction rates obtained previous-ly at 293.88 K and in the present study were correlated. The dependence of reaction rates on the composition of hexane-nitrobenzene mixed solvent was correlated with fairly good agreement by introducing interaction parameters estimated with vapor-liquid equilibria into the regular solution model.

Original languageEnglish
Number of pages1
Journalkagaku kogaku ronbunshu
Volume25
Issue number3
DOIs
Publication statusPublished - 1999

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

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