Measurement of the Md3+/Md2+ reduction potential studied with flow electrolytic chromatography

Atsushi Toyoshima, Zijie Li, Masato Asai, Nozomi Sato, Tetsuya K. Sato, Takahiro Kikuchi, Yusuke Kaneya, Yoshihiro Kitatsuji, Kazuaki Tsukada, Yuichiro Nagame, Matthias Schädel, Kazuhiro Ooe, Yoshitaka Kasamatsu, Atsushi Shinohara, Hiromitsu Haba, Julia Even

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Abstract

The reduction behavior of mendelevium (Md) was studied using a flow electrolytic chromatography apparatus. By application of the appropriate potentials on the chromatography column, the more stable Md3+ is reduced to Md2+. The reduction potential of the Md3+ + e- → Md2+ couple was determined to be -0.16 ± 0.05 V versus a normal hydrogen electrode.

Original languageEnglish
Pages (from-to)12311-12313
Number of pages3
JournalInorganic chemistry
Volume52
Issue number21
DOIs
Publication statusPublished - Nov 4 2013

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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    Toyoshima, A., Li, Z., Asai, M., Sato, N., Sato, T. K., Kikuchi, T., Kaneya, Y., Kitatsuji, Y., Tsukada, K., Nagame, Y., Schädel, M., Ooe, K., Kasamatsu, Y., Shinohara, A., Haba, H., & Even, J. (2013). Measurement of the Md3+/Md2+ reduction potential studied with flow electrolytic chromatography. Inorganic chemistry, 52(21), 12311-12313. https://doi.org/10.1021/ic401571h