Measurements of PvT Properties, Saturated Densities, and Critical Parameters for 3,3,3-Trifluoropropene (HFO1243zf)

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Abstract

Measurements of PvT properties, saturated densities, and critical parameters were carried out for a low-GWP refrigerant: 3,3,3-trifluoropropene (HFO1243zf, CF3CH=CH2). Seventy-five PvT property data points along seven isochores around the critical point were obtained in the temperature range from 328 to 430 K, in the density range between 50 and 899 kg m-3, and at pressures up to 6.9 MPa by the isochoric method. Fourteen saturated densities were obtained by the observation of meniscus disappearance in the critical region. On the basis of these measurements, the critical parameters of Tc = 376.93 ± 0.01 K and ρc = 414 ± 3 kg m-3 were determined. The present results are compared to an available equation of state.

Original languageEnglish
Pages (from-to)3818-3822
Number of pages5
JournalJournal of Chemical and Engineering Data
Volume63
Issue number10
DOIs
Publication statusPublished - Oct 11 2018

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Isochores
Refrigerants
Equations of state
Temperature

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

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title = "Measurements of PvT Properties, Saturated Densities, and Critical Parameters for 3,3,3-Trifluoropropene (HFO1243zf)",
abstract = "Measurements of PvT properties, saturated densities, and critical parameters were carried out for a low-GWP refrigerant: 3,3,3-trifluoropropene (HFO1243zf, CF3CH=CH2). Seventy-five PvT property data points along seven isochores around the critical point were obtained in the temperature range from 328 to 430 K, in the density range between 50 and 899 kg m-3, and at pressures up to 6.9 MPa by the isochoric method. Fourteen saturated densities were obtained by the observation of meniscus disappearance in the critical region. On the basis of these measurements, the critical parameters of Tc = 376.93 ± 0.01 K and ρc = 414 ± 3 kg m-3 were determined. The present results are compared to an available equation of state.",
author = "Yukihiro Higashi and Naoya Sakoda",
year = "2018",
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language = "English",
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pages = "3818--3822",
journal = "Journal of Chemical & Engineering Data",
issn = "0021-9568",
publisher = "American Chemical Society",
number = "10",

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T1 - Measurements of PvT Properties, Saturated Densities, and Critical Parameters for 3,3,3-Trifluoropropene (HFO1243zf)

AU - Higashi, Yukihiro

AU - Sakoda, Naoya

PY - 2018/10/11

Y1 - 2018/10/11

N2 - Measurements of PvT properties, saturated densities, and critical parameters were carried out for a low-GWP refrigerant: 3,3,3-trifluoropropene (HFO1243zf, CF3CH=CH2). Seventy-five PvT property data points along seven isochores around the critical point were obtained in the temperature range from 328 to 430 K, in the density range between 50 and 899 kg m-3, and at pressures up to 6.9 MPa by the isochoric method. Fourteen saturated densities were obtained by the observation of meniscus disappearance in the critical region. On the basis of these measurements, the critical parameters of Tc = 376.93 ± 0.01 K and ρc = 414 ± 3 kg m-3 were determined. The present results are compared to an available equation of state.

AB - Measurements of PvT properties, saturated densities, and critical parameters were carried out for a low-GWP refrigerant: 3,3,3-trifluoropropene (HFO1243zf, CF3CH=CH2). Seventy-five PvT property data points along seven isochores around the critical point were obtained in the temperature range from 328 to 430 K, in the density range between 50 and 899 kg m-3, and at pressures up to 6.9 MPa by the isochoric method. Fourteen saturated densities were obtained by the observation of meniscus disappearance in the critical region. On the basis of these measurements, the critical parameters of Tc = 376.93 ± 0.01 K and ρc = 414 ± 3 kg m-3 were determined. The present results are compared to an available equation of state.

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