Measurements of the isobaric specific heat capacity for 1,1,1-trifluoroethane (R143a), pentafluoroethane (R125), and difluoromethane (R32) in the liquid phase

Katsuyuki Tanaka, Yukihiro Higashi

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2 Citations (Scopus)

Abstract

Measurements of the isobaric specific heat capacity for the hydrocarbons 1,1,1-trifluoroethane (R143a), pentafluoroethane (R125), and difluoromethane (R32) were carried out in the liquid phase at a pressure of 5 MPa by using a batch type calorimeter equipped with a metal bellows. Ten data points of the isobaric specific heat capacity for R143a, 11 data points for R125, and seven data points for R32 were obtained in the temperature range from (310 to 350) K and at a pressure of 5 MPa. The experimental uncertainties are estimated to be 5 mK for temperature, 3 kPa for pressure, and 5.2 % for isobaric specific heat capacity. The present results were compared with the literature data and the values calculated from the equation of state. The correlations of the isobaric specific heat capacity were formulated as a function of temperature at a pressure of 5 MPa. Maximum deviations of the present results from correlations were 1.4 % for R143a, 1.5 % for R125, and 0.9 % for R32, respectively.

Original languageEnglish
Pages (from-to)1516-1518
Number of pages3
JournalJournal of Chemical and Engineering Data
Volume55
Issue number4
DOIs
Publication statusPublished - Apr 8 2010
Externally publishedYes

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Specific heat
Liquids
Bellows
pentafluoroethane
1,1,1-trifluoroethane
difluoromethane
Hydrocarbons
Calorimeters
Equations of state
Temperature
Metals

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

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title = "Measurements of the isobaric specific heat capacity for 1,1,1-trifluoroethane (R143a), pentafluoroethane (R125), and difluoromethane (R32) in the liquid phase",
abstract = "Measurements of the isobaric specific heat capacity for the hydrocarbons 1,1,1-trifluoroethane (R143a), pentafluoroethane (R125), and difluoromethane (R32) were carried out in the liquid phase at a pressure of 5 MPa by using a batch type calorimeter equipped with a metal bellows. Ten data points of the isobaric specific heat capacity for R143a, 11 data points for R125, and seven data points for R32 were obtained in the temperature range from (310 to 350) K and at a pressure of 5 MPa. The experimental uncertainties are estimated to be 5 mK for temperature, 3 kPa for pressure, and 5.2 {\%} for isobaric specific heat capacity. The present results were compared with the literature data and the values calculated from the equation of state. The correlations of the isobaric specific heat capacity were formulated as a function of temperature at a pressure of 5 MPa. Maximum deviations of the present results from correlations were 1.4 {\%} for R143a, 1.5 {\%} for R125, and 0.9 {\%} for R32, respectively.",
author = "Katsuyuki Tanaka and Yukihiro Higashi",
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journal = "Journal of Chemical & Engineering Data",
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T1 - Measurements of the isobaric specific heat capacity for 1,1,1-trifluoroethane (R143a), pentafluoroethane (R125), and difluoromethane (R32) in the liquid phase

AU - Tanaka, Katsuyuki

AU - Higashi, Yukihiro

PY - 2010/4/8

Y1 - 2010/4/8

N2 - Measurements of the isobaric specific heat capacity for the hydrocarbons 1,1,1-trifluoroethane (R143a), pentafluoroethane (R125), and difluoromethane (R32) were carried out in the liquid phase at a pressure of 5 MPa by using a batch type calorimeter equipped with a metal bellows. Ten data points of the isobaric specific heat capacity for R143a, 11 data points for R125, and seven data points for R32 were obtained in the temperature range from (310 to 350) K and at a pressure of 5 MPa. The experimental uncertainties are estimated to be 5 mK for temperature, 3 kPa for pressure, and 5.2 % for isobaric specific heat capacity. The present results were compared with the literature data and the values calculated from the equation of state. The correlations of the isobaric specific heat capacity were formulated as a function of temperature at a pressure of 5 MPa. Maximum deviations of the present results from correlations were 1.4 % for R143a, 1.5 % for R125, and 0.9 % for R32, respectively.

AB - Measurements of the isobaric specific heat capacity for the hydrocarbons 1,1,1-trifluoroethane (R143a), pentafluoroethane (R125), and difluoromethane (R32) were carried out in the liquid phase at a pressure of 5 MPa by using a batch type calorimeter equipped with a metal bellows. Ten data points of the isobaric specific heat capacity for R143a, 11 data points for R125, and seven data points for R32 were obtained in the temperature range from (310 to 350) K and at a pressure of 5 MPa. The experimental uncertainties are estimated to be 5 mK for temperature, 3 kPa for pressure, and 5.2 % for isobaric specific heat capacity. The present results were compared with the literature data and the values calculated from the equation of state. The correlations of the isobaric specific heat capacity were formulated as a function of temperature at a pressure of 5 MPa. Maximum deviations of the present results from correlations were 1.4 % for R143a, 1.5 % for R125, and 0.9 % for R32, respectively.

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